Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy
Escalating concern over global warming, which is mostly associated with deforestation, has led to the development of new classes of materials that can replace wood and better utilise natural resources. Presently, waste is a significant factor in recycling. In this regard, one of the leading contribu...
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Elsevier
2024-02-01
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844024013185 |
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author | Anam Khan Alka Mishra Ravi Patidar Asokan Pappu |
author_facet | Anam Khan Alka Mishra Ravi Patidar Asokan Pappu |
author_sort | Anam Khan |
collection | DOAJ |
description | Escalating concern over global warming, which is mostly associated with deforestation, has led to the development of new classes of materials that can replace wood and better utilise natural resources. Presently, waste is a significant factor in recycling. In this regard, one of the leading contributors to waste is agricultural waste, which includes dried branches, leaves of trees, plants, and other organic materials. In the current study, waste from corn agriculture was utilised as a potential reinforcement for the fabrication of corn stalk-low density polyethylene (CS-LDPE) composites via an injection moulding technique at 170 °C. The different parameters were assessed to develop composites using CS, including physico-chemical, macromolecular, mineralogical, elemental, and morphological analysis. The amount of corn stalk (CS) was varied from 10 to 50 wt% with respect to the polymer. The mechanical, physical and thermal performance of the composites was examined. The density and water absorption of the composites were found to remain within the ranges of 1.00–1.11 g/cm3 and 0.22–1.01 %, respectively, whereas these parameters increased as the proportion of CS increased. The thermal conductivity decreases with the addition of CS from 0.36964 ± 0.020 to 0.22388 ± 0.002 W/mK. It was observed that adding CS to the composites increased their tensile and flexural properties, but decreased their impact strength. The maximum flexural strength of 14.40 ± 1.558 MPa, flexural modulus of 752.53 ± 180.409 MPa, tensile strength of 10.49 ± 0.946 MPa and tensile modulus of 539.79 ± 91.044 MPa were observed with a 50 % CS content. The results suggest that these materials have considerable potential to serve as a cost-effective substitute for the conventional lignocellulosic fillers in the manufacturing of wood-plastic composites. |
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spelling | doaj.art-928ba15fcbbe421daa21bc7b285883cb2024-03-09T09:25:19ZengElsevierHeliyon2405-84402024-02-01104e25287Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economyAnam Khan0Alka Mishra1Ravi Patidar2Asokan Pappu3CSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh, 462026, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India; Corresponding author. CSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh 462026, India.CSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh, 462026, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, IndiaCSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh, 462026, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, IndiaCSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh, 462026, India; Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India; Corresponding author. CSIR - Advanced Materials and Processes Research Institute (AMPRI), Near Habibganj Naka, Hoshangabad Road, Bhopal, Madhya Pradesh 462026, India.Escalating concern over global warming, which is mostly associated with deforestation, has led to the development of new classes of materials that can replace wood and better utilise natural resources. Presently, waste is a significant factor in recycling. In this regard, one of the leading contributors to waste is agricultural waste, which includes dried branches, leaves of trees, plants, and other organic materials. In the current study, waste from corn agriculture was utilised as a potential reinforcement for the fabrication of corn stalk-low density polyethylene (CS-LDPE) composites via an injection moulding technique at 170 °C. The different parameters were assessed to develop composites using CS, including physico-chemical, macromolecular, mineralogical, elemental, and morphological analysis. The amount of corn stalk (CS) was varied from 10 to 50 wt% with respect to the polymer. The mechanical, physical and thermal performance of the composites was examined. The density and water absorption of the composites were found to remain within the ranges of 1.00–1.11 g/cm3 and 0.22–1.01 %, respectively, whereas these parameters increased as the proportion of CS increased. The thermal conductivity decreases with the addition of CS from 0.36964 ± 0.020 to 0.22388 ± 0.002 W/mK. It was observed that adding CS to the composites increased their tensile and flexural properties, but decreased their impact strength. The maximum flexural strength of 14.40 ± 1.558 MPa, flexural modulus of 752.53 ± 180.409 MPa, tensile strength of 10.49 ± 0.946 MPa and tensile modulus of 539.79 ± 91.044 MPa were observed with a 50 % CS content. The results suggest that these materials have considerable potential to serve as a cost-effective substitute for the conventional lignocellulosic fillers in the manufacturing of wood-plastic composites.http://www.sciencedirect.com/science/article/pii/S2405844024013185Corn stalkLDPECrop residueInjection mouldingSEMMechanical properties |
spellingShingle | Anam Khan Alka Mishra Ravi Patidar Asokan Pappu Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy Heliyon Corn stalk LDPE Crop residue Injection moulding SEM Mechanical properties |
title | Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy |
title_full | Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy |
title_fullStr | Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy |
title_full_unstemmed | Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy |
title_short | Effect of lignocellulosic corn stalk on mechanical, physical, and thermal properties of injection moulded low density polyethylene composites: An approach towards a circular economy |
title_sort | effect of lignocellulosic corn stalk on mechanical physical and thermal properties of injection moulded low density polyethylene composites an approach towards a circular economy |
topic | Corn stalk LDPE Crop residue Injection moulding SEM Mechanical properties |
url | http://www.sciencedirect.com/science/article/pii/S2405844024013185 |
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