Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
Abstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several...
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Format: | Article |
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SpringerOpen
2018-01-01
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Series: | Applied Water Science |
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Online Access: | http://link.springer.com/article/10.1007/s13201-018-0651-8 |
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author | Upama Devi Krishna G. Bhattacharyya |
author_facet | Upama Devi Krishna G. Bhattacharyya |
author_sort | Upama Devi |
collection | DOAJ |
description | Abstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd < Co < Cu < Cr < Zn < Mn. The relative distribution of the metals showed that Cd was available mostly in the exchangeable and the carbonate bound fractions, which were the most mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category. |
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language | English |
last_indexed | 2024-12-19T20:04:53Z |
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spelling | doaj.art-929c481404344ae09b1f56eafdbdd57a2022-12-21T20:07:31ZengSpringerOpenApplied Water Science2190-54872190-54952018-01-018111410.1007/s13201-018-0651-8Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, IndiaUpama Devi0Krishna G. Bhattacharyya1Department of Chemistry, Gauhati UniversityDepartment of Chemistry, Gauhati UniversityAbstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd < Co < Cu < Cr < Zn < Mn. The relative distribution of the metals showed that Cd was available mostly in the exchangeable and the carbonate bound fractions, which were the most mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category.http://link.springer.com/article/10.1007/s13201-018-0651-8Runoff sedimentSpeciationSequential extractionMetals |
spellingShingle | Upama Devi Krishna G. Bhattacharyya Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India Applied Water Science Runoff sediment Speciation Sequential extraction Metals |
title | Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India |
title_full | Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India |
title_fullStr | Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India |
title_full_unstemmed | Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India |
title_short | Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India |
title_sort | mobility and bioavailability of cd co cr cu mn and zn in surface runoff sediments in the urban catchment area of guwahati india |
topic | Runoff sediment Speciation Sequential extraction Metals |
url | http://link.springer.com/article/10.1007/s13201-018-0651-8 |
work_keys_str_mv | AT upamadevi mobilityandbioavailabilityofcdcocrcumnandzninsurfacerunoffsedimentsintheurbancatchmentareaofguwahatiindia AT krishnagbhattacharyya mobilityandbioavailabilityofcdcocrcumnandzninsurfacerunoffsedimentsintheurbancatchmentareaofguwahatiindia |