Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India

Abstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several...

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Main Authors: Upama Devi, Krishna G. Bhattacharyya
Format: Article
Language:English
Published: SpringerOpen 2018-01-01
Series:Applied Water Science
Subjects:
Online Access:http://link.springer.com/article/10.1007/s13201-018-0651-8
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author Upama Devi
Krishna G. Bhattacharyya
author_facet Upama Devi
Krishna G. Bhattacharyya
author_sort Upama Devi
collection DOAJ
description Abstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd < Co < Cu < Cr < Zn < Mn. The relative distribution of the metals showed that Cd was available mostly in the exchangeable and the carbonate bound fractions, which were the most mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category.
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spelling doaj.art-929c481404344ae09b1f56eafdbdd57a2022-12-21T20:07:31ZengSpringerOpenApplied Water Science2190-54872190-54952018-01-018111410.1007/s13201-018-0651-8Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, IndiaUpama Devi0Krishna G. Bhattacharyya1Department of Chemistry, Gauhati UniversityDepartment of Chemistry, Gauhati UniversityAbstract The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd < Co < Cu < Cr < Zn < Mn. The relative distribution of the metals showed that Cd was available mostly in the exchangeable and the carbonate bound fractions, which were the most mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category.http://link.springer.com/article/10.1007/s13201-018-0651-8Runoff sedimentSpeciationSequential extractionMetals
spellingShingle Upama Devi
Krishna G. Bhattacharyya
Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
Applied Water Science
Runoff sediment
Speciation
Sequential extraction
Metals
title Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
title_full Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
title_fullStr Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
title_full_unstemmed Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
title_short Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India
title_sort mobility and bioavailability of cd co cr cu mn and zn in surface runoff sediments in the urban catchment area of guwahati india
topic Runoff sediment
Speciation
Sequential extraction
Metals
url http://link.springer.com/article/10.1007/s13201-018-0651-8
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AT krishnagbhattacharyya mobilityandbioavailabilityofcdcocrcumnandzninsurfacerunoffsedimentsintheurbancatchmentareaofguwahatiindia