Fullerene Nanoarchitectonics with Shape-Shifting

This short review article introduces several examples of self-assembly-based structural formation and shape-shifting using very simple molecular units, fullerenes (C<sub>60</sub>, C<sub>70</sub>, and their derivatives), as fullerene nanoarchitectonics. Fullerene molecules are...

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Main Authors: Katsuhiko Ariga, Lok Kumar Shrestha
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/10/2280
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author Katsuhiko Ariga
Lok Kumar Shrestha
author_facet Katsuhiko Ariga
Lok Kumar Shrestha
author_sort Katsuhiko Ariga
collection DOAJ
description This short review article introduces several examples of self-assembly-based structural formation and shape-shifting using very simple molecular units, fullerenes (C<sub>60</sub>, C<sub>70</sub>, and their derivatives), as fullerene nanoarchitectonics. Fullerene molecules are suitable units for the basic science of self-assembly because they are simple zero-dimensional objects with only a single elemental component, carbon, without any charged or interactive functional groups. In this review article, self-assembly of fullerene molecules and their shape-shifting are introduced as fullerene nanoarchitectonics. An outline and a background of fullerene nanoarchitectonics are first described, followed by various demonstrations, including fabrication of various fullerene nanostructures, such as rods on the cube, holes in the cube, interior channels in the cube, and fullerene micro-horns, and also a demonstration of a new concept, supramolecular differentiation.
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spelling doaj.art-92a6e3cee9984a208d7ea6b50b307f012023-11-20T00:34:51ZengMDPI AGMaterials1996-19442020-05-011310228010.3390/ma13102280Fullerene Nanoarchitectonics with Shape-ShiftingKatsuhiko Ariga0Lok Kumar Shrestha1International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, JapanInternational Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, JapanThis short review article introduces several examples of self-assembly-based structural formation and shape-shifting using very simple molecular units, fullerenes (C<sub>60</sub>, C<sub>70</sub>, and their derivatives), as fullerene nanoarchitectonics. Fullerene molecules are suitable units for the basic science of self-assembly because they are simple zero-dimensional objects with only a single elemental component, carbon, without any charged or interactive functional groups. In this review article, self-assembly of fullerene molecules and their shape-shifting are introduced as fullerene nanoarchitectonics. An outline and a background of fullerene nanoarchitectonics are first described, followed by various demonstrations, including fabrication of various fullerene nanostructures, such as rods on the cube, holes in the cube, interior channels in the cube, and fullerene micro-horns, and also a demonstration of a new concept, supramolecular differentiation.https://www.mdpi.com/1996-1944/13/10/2280fullereneinterfacenanoarchitectonicsself-assemblyshape-shift
spellingShingle Katsuhiko Ariga
Lok Kumar Shrestha
Fullerene Nanoarchitectonics with Shape-Shifting
Materials
fullerene
interface
nanoarchitectonics
self-assembly
shape-shift
title Fullerene Nanoarchitectonics with Shape-Shifting
title_full Fullerene Nanoarchitectonics with Shape-Shifting
title_fullStr Fullerene Nanoarchitectonics with Shape-Shifting
title_full_unstemmed Fullerene Nanoarchitectonics with Shape-Shifting
title_short Fullerene Nanoarchitectonics with Shape-Shifting
title_sort fullerene nanoarchitectonics with shape shifting
topic fullerene
interface
nanoarchitectonics
self-assembly
shape-shift
url https://www.mdpi.com/1996-1944/13/10/2280
work_keys_str_mv AT katsuhikoariga fullerenenanoarchitectonicswithshapeshifting
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