{4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II)
In the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. Th...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812009397 |
| _version_ | 1818083352141365248 |
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| author | Hadi Kargar Reza Kia Mahbubeh Haghshenas Muhammad Nawaz Tahir |
| author_facet | Hadi Kargar Reza Kia Mahbubeh Haghshenas Muhammad Nawaz Tahir |
| author_sort | Hadi Kargar |
| collection | DOAJ |
| description | In the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) Å]. |
| first_indexed | 2024-12-10T19:36:38Z |
| format | Article |
| id | doaj.art-92e7411c57ac4ea3a94d6d27ae86ab24 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:36:38Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-92e7411c57ac4ea3a94d6d27ae86ab242022-12-22T01:36:08ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m392m39210.1107/S1600536812009397{4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II)Hadi KargarReza KiaMahbubeh HaghshenasMuhammad Nawaz TahirIn the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812009397 |
| spellingShingle | Hadi Kargar Reza Kia Mahbubeh Haghshenas Muhammad Nawaz Tahir {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) Acta Crystallographica Section E |
| title | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_full | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_fullStr | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_full_unstemmed | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_short | {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II) |
| title_sort | 4 4 amp 8242 6 6 amp 8242 tetrabromo 2 2 amp 8242 2 2 dimethylpropane 1 3 diyl bis nitrilomethanylylidene diphenolato copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812009397 |
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