Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
In this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to...
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Language: | English |
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Siberian Federal University
2019-09-01
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Series: | Журнал Сибирского федерального университета: Серия Биология |
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Online Access: | http://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdf |
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author | Preetha Balakrishnan Sreerag Gopi V. G. Geethamma Sabu Thomas |
author_facet | Preetha Balakrishnan Sreerag Gopi V. G. Geethamma Sabu Thomas |
author_sort | Preetha Balakrishnan |
collection | DOAJ |
description | In this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to neat film. The tensile properties were fit with theoretical predictions. Tensile strength increased with CNF loading and reached up to 4.682 MPa (TPS+3 wt.% CNF) from 1.58 MPa (neat TPS), an improvement of ~196% over the neat polymer. The addition of cellulose nanofiber improved the barrier properties of films by creating a tortuous path for penetrant molecules. Gas transport behavior of CNF-based TPS nanocomposite films was explored using O2 gas. A 56% decrease (relative to neat TPS) in oxygen permeability of the nanocomposite membranes was achieved by adding only 3 wt.% CNF. The oxygen permeability data were fit with two theoretical models |
first_indexed | 2024-12-11T23:14:08Z |
format | Article |
id | doaj.art-9302216c52474617afe216c7c1068041 |
institution | Directory Open Access Journal |
issn | 1997-1389 2313-5530 |
language | English |
last_indexed | 2024-12-11T23:14:08Z |
publishDate | 2019-09-01 |
publisher | Siberian Federal University |
record_format | Article |
series | Журнал Сибирского федерального университета: Серия Биология |
spelling | doaj.art-9302216c52474617afe216c7c10680412022-12-22T00:46:36ZengSiberian Federal UniversityЖурнал Сибирского федерального университета: Серия Биология1997-13892313-55302019-09-0112328730110.17516/1997-1389-0303http://elib.sfu-kras.ru/handle/2311/125600Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging ApplicationsPreetha Balakrishnan0Sreerag Gopi1V. G. Geethamma2Sabu Thomas3International and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaADSO Naturals Pvt., Ltd. 2/5 RMV Second Stage, Sanjay Nagar, Bangalore, 560094, IndiaInternational and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaInternational and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaIn this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to neat film. The tensile properties were fit with theoretical predictions. Tensile strength increased with CNF loading and reached up to 4.682 MPa (TPS+3 wt.% CNF) from 1.58 MPa (neat TPS), an improvement of ~196% over the neat polymer. The addition of cellulose nanofiber improved the barrier properties of films by creating a tortuous path for penetrant molecules. Gas transport behavior of CNF-based TPS nanocomposite films was explored using O2 gas. A 56% decrease (relative to neat TPS) in oxygen permeability of the nanocomposite membranes was achieved by adding only 3 wt.% CNF. The oxygen permeability data were fit with two theoretical modelshttp://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdfstarchnanofibermechanicalpermeabilitymodeling |
spellingShingle | Preetha Balakrishnan Sreerag Gopi V. G. Geethamma Sabu Thomas Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications Журнал Сибирского федерального университета: Серия Биология starch nanofiber mechanical permeability modeling |
title | Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications |
title_full | Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications |
title_fullStr | Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications |
title_full_unstemmed | Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications |
title_short | Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications |
title_sort | mechanical and permeability properties of thermoplastic starch composites reinforced with cellulose nanofiber for packaging applications |
topic | starch nanofiber mechanical permeability modeling |
url | http://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdf |
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