Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications

In this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to...

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Main Authors: Preetha Balakrishnan, Sreerag Gopi, V. G. Geethamma, Sabu Thomas
Format: Article
Language:English
Published: Siberian Federal University 2019-09-01
Series:Журнал Сибирского федерального университета: Серия Биология
Subjects:
Online Access:http://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdf
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author Preetha Balakrishnan
Sreerag Gopi
V. G. Geethamma
Sabu Thomas
author_facet Preetha Balakrishnan
Sreerag Gopi
V. G. Geethamma
Sabu Thomas
author_sort Preetha Balakrishnan
collection DOAJ
description In this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to neat film. The tensile properties were fit with theoretical predictions. Tensile strength increased with CNF loading and reached up to 4.682 MPa (TPS+3 wt.% CNF) from 1.58 MPa (neat TPS), an improvement of ~196% over the neat polymer. The addition of cellulose nanofiber improved the barrier properties of films by creating a tortuous path for penetrant molecules. Gas transport behavior of CNF-based TPS nanocomposite films was explored using O2 gas. A 56% decrease (relative to neat TPS) in oxygen permeability of the nanocomposite membranes was achieved by adding only 3 wt.% CNF. The oxygen permeability data were fit with two theoretical models
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spelling doaj.art-9302216c52474617afe216c7c10680412022-12-22T00:46:36ZengSiberian Federal UniversityЖурнал Сибирского федерального университета: Серия Биология1997-13892313-55302019-09-0112328730110.17516/1997-1389-0303http://elib.sfu-kras.ru/handle/2311/125600Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging ApplicationsPreetha Balakrishnan0Sreerag Gopi1V. G. Geethamma2Sabu Thomas3International and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaADSO Naturals Pvt., Ltd. 2/5 RMV Second Stage, Sanjay Nagar, Bangalore, 560094, IndiaInternational and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaInternational and Inter University Center for Nanoscience and Nanotechnology, Mahatma Gandhi University Kottayam, Kerala, 686560, IndiaIn this study, a facile, ecofriendly nanocomposite based on glycerol-plasticized thermoplastic potato starch (TPS) containing 0-4 wt.% cellulose nanofiber (CNF) from pineapple leaf was prepared by the solution casting technique. The nanocomposite films showed better mechanical properties compared to neat film. The tensile properties were fit with theoretical predictions. Tensile strength increased with CNF loading and reached up to 4.682 MPa (TPS+3 wt.% CNF) from 1.58 MPa (neat TPS), an improvement of ~196% over the neat polymer. The addition of cellulose nanofiber improved the barrier properties of films by creating a tortuous path for penetrant molecules. Gas transport behavior of CNF-based TPS nanocomposite films was explored using O2 gas. A 56% decrease (relative to neat TPS) in oxygen permeability of the nanocomposite membranes was achieved by adding only 3 wt.% CNF. The oxygen permeability data were fit with two theoretical modelshttp://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdfstarchnanofibermechanicalpermeabilitymodeling
spellingShingle Preetha Balakrishnan
Sreerag Gopi
V. G. Geethamma
Sabu Thomas
Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
Журнал Сибирского федерального университета: Серия Биология
starch
nanofiber
mechanical
permeability
modeling
title Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
title_full Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
title_fullStr Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
title_full_unstemmed Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
title_short Mechanical and Permeability Properties of Thermoplastic Starch Composites Reinforced with Cellulose Nanofiber for Packaging Applications
title_sort mechanical and permeability properties of thermoplastic starch composites reinforced with cellulose nanofiber for packaging applications
topic starch
nanofiber
mechanical
permeability
modeling
url http://elib.sfu-kras.ru/bitstream/2311/125600/1/07_Balakrishnan.pdf
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AT vggeethamma mechanicalandpermeabilitypropertiesofthermoplasticstarchcompositesreinforcedwithcellulosenanofiberforpackagingapplications
AT sabuthomas mechanicalandpermeabilitypropertiesofthermoplasticstarchcompositesreinforcedwithcellulosenanofiberforpackagingapplications