Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application

Persulfate-based in situ chemical oxidation (ISCO) has been increasingly used for the remediation of contaminated groundwater and soil. In recent years, there have been numerous studies in the literature on all aspects of the activation of persulfate for contaminant removal at the laboratory scale,...

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Main Authors: Yan Li, Guansheng Liu, Jinping He, Hua Zhong
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/13/3/1304
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author Yan Li
Guansheng Liu
Jinping He
Hua Zhong
author_facet Yan Li
Guansheng Liu
Jinping He
Hua Zhong
author_sort Yan Li
collection DOAJ
description Persulfate-based in situ chemical oxidation (ISCO) has been increasingly used for the remediation of contaminated groundwater and soil. In recent years, there have been numerous studies in the literature on all aspects of the activation of persulfate for contaminant removal at the laboratory scale, including the ways and mechanisms for the activation, the pathways of contaminant degradation, the factors associated with the activation performance, the methods characterizing the processes, etc. In contrast, studies in the literature on the practical use of the activated persulfate at the field scale are fewer, and at the same time have not been reviewed in an organized way. This review was initiated to summarize on the current research on the applications of activated persulfate for actual site remediation, and to extract the knowledge necessary for the formation of applicable technologies. The remediation efficiency and mechanism of activated persulfates by heat, alkaline, metal-based, and electrokinetic activated technologies are described. The major factors including pH, the persistence of persulfate, and the radius of influence and soil property during ISCO remediation applications were presented and discussed. Finally, the rebound process and impact towards microbial communities after in-situ chemical oxidation on site application were discussed.
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spelling doaj.art-9303a582ccd24e839b35bd9cf8eb30502023-11-16T16:03:31ZengMDPI AGApplied Sciences2076-34172023-01-01133130410.3390/app13031304Activation of Persulfate for Groundwater Remediation: From Bench Studies to ApplicationYan Li0Guansheng Liu1Jinping He2Hua Zhong3State Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430070, ChinaState Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430070, ChinaState Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430070, ChinaState Key Laboratory of Water Resources and Hydropower Engineering Science, Wuhan University, Wuhan 430070, ChinaPersulfate-based in situ chemical oxidation (ISCO) has been increasingly used for the remediation of contaminated groundwater and soil. In recent years, there have been numerous studies in the literature on all aspects of the activation of persulfate for contaminant removal at the laboratory scale, including the ways and mechanisms for the activation, the pathways of contaminant degradation, the factors associated with the activation performance, the methods characterizing the processes, etc. In contrast, studies in the literature on the practical use of the activated persulfate at the field scale are fewer, and at the same time have not been reviewed in an organized way. This review was initiated to summarize on the current research on the applications of activated persulfate for actual site remediation, and to extract the knowledge necessary for the formation of applicable technologies. The remediation efficiency and mechanism of activated persulfates by heat, alkaline, metal-based, and electrokinetic activated technologies are described. The major factors including pH, the persistence of persulfate, and the radius of influence and soil property during ISCO remediation applications were presented and discussed. Finally, the rebound process and impact towards microbial communities after in-situ chemical oxidation on site application were discussed.https://www.mdpi.com/2076-3417/13/3/1304persulfate activationin situ chemical oxidationdegradation of organic pollutantsgroundwater remediation
spellingShingle Yan Li
Guansheng Liu
Jinping He
Hua Zhong
Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
Applied Sciences
persulfate activation
in situ chemical oxidation
degradation of organic pollutants
groundwater remediation
title Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
title_full Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
title_fullStr Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
title_full_unstemmed Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
title_short Activation of Persulfate for Groundwater Remediation: From Bench Studies to Application
title_sort activation of persulfate for groundwater remediation from bench studies to application
topic persulfate activation
in situ chemical oxidation
degradation of organic pollutants
groundwater remediation
url https://www.mdpi.com/2076-3417/13/3/1304
work_keys_str_mv AT yanli activationofpersulfateforgroundwaterremediationfrombenchstudiestoapplication
AT guanshengliu activationofpersulfateforgroundwaterremediationfrombenchstudiestoapplication
AT jinpinghe activationofpersulfateforgroundwaterremediationfrombenchstudiestoapplication
AT huazhong activationofpersulfateforgroundwaterremediationfrombenchstudiestoapplication