Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances

Organic carbonates are considered the chemicals of the future. In particular, propylene carbonate is widely used as a non-reactive solvent, plasticizer, fuel additive, and reagent, especially in the production of environmentally friendly polymers that are not harmful to human health. This paper revi...

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Main Authors: Łukasz Kotyrba, Anna Chrobok, Agnieszka Siewniak
Format: Article
Language:English
Published: MDPI AG 2022-03-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/3/309
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author Łukasz Kotyrba
Anna Chrobok
Agnieszka Siewniak
author_facet Łukasz Kotyrba
Anna Chrobok
Agnieszka Siewniak
author_sort Łukasz Kotyrba
collection DOAJ
description Organic carbonates are considered the chemicals of the future. In particular, propylene carbonate is widely used as a non-reactive solvent, plasticizer, fuel additive, and reagent, especially in the production of environmentally friendly polymers that are not harmful to human health. This paper reviews recent literature findings regarding the development of propylene carbonate synthetic methods starting from propane-1,2-diol and urea. The ammonia formed during the synthesis is recycled to obtain urea from carbon dioxide.
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spelling doaj.art-931a187f765b4bb39422fa6777a2e40d2023-11-24T00:42:41ZengMDPI AGCatalysts2073-43442022-03-0112330910.3390/catal12030309Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent AdvancesŁukasz Kotyrba0Anna Chrobok1Agnieszka Siewniak2Łukasiewicz Research Network—Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, 47-225 Kędzierzyn-Koźle, PolandDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, PolandDepartment of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, PolandOrganic carbonates are considered the chemicals of the future. In particular, propylene carbonate is widely used as a non-reactive solvent, plasticizer, fuel additive, and reagent, especially in the production of environmentally friendly polymers that are not harmful to human health. This paper reviews recent literature findings regarding the development of propylene carbonate synthetic methods starting from propane-1,2-diol and urea. The ammonia formed during the synthesis is recycled to obtain urea from carbon dioxide.https://www.mdpi.com/2073-4344/12/3/309propylene carbonateurea alcoholysispropylene glycol
spellingShingle Łukasz Kotyrba
Anna Chrobok
Agnieszka Siewniak
Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
Catalysts
propylene carbonate
urea alcoholysis
propylene glycol
title Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
title_full Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
title_fullStr Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
title_full_unstemmed Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
title_short Synthesis of Propylene Carbonate by Urea Alcoholysis—Recent Advances
title_sort synthesis of propylene carbonate by urea alcoholysis recent advances
topic propylene carbonate
urea alcoholysis
propylene glycol
url https://www.mdpi.com/2073-4344/12/3/309
work_keys_str_mv AT łukaszkotyrba synthesisofpropylenecarbonatebyureaalcoholysisrecentadvances
AT annachrobok synthesisofpropylenecarbonatebyureaalcoholysisrecentadvances
AT agnieszkasiewniak synthesisofpropylenecarbonatebyureaalcoholysisrecentadvances