Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry

Coal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to managem...

Full description

Bibliographic Details
Main Authors: Hiroyuki Masaki, Shinji Yasuike, Kenji Matsumoto, Masaru Tajiri, Yoshihiro Yoshioka, Seiji Inoba
Format: Article
Language:English
Published: Elsevier 2018-08-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844018317778
_version_ 1818279460775919616
author Hiroyuki Masaki
Shinji Yasuike
Kenji Matsumoto
Masaru Tajiri
Yoshihiro Yoshioka
Seiji Inoba
author_facet Hiroyuki Masaki
Shinji Yasuike
Kenji Matsumoto
Masaru Tajiri
Yoshihiro Yoshioka
Seiji Inoba
author_sort Hiroyuki Masaki
collection DOAJ
description Coal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to management and/or screening their leachability. However, satisfactory methods to measure boron alone have not been reported. In this study, we developed an instrument for the non-contact analysis of boron in CFA samples. This simple instrument consisted of a sealed neutron source, a moderator, a proportional counter, and a signal processing device. The analysis method, based on thermal neutron absorptiometry, can rapidly measure the boron content within five minutes without pre-treatment. We applied the developed equipment to over 200 CFA samples, and excellent correlation was obtained between the proposed and traditional methods. These results indicated that the developed equipment is useful for managing and/or screening boron in CFA.
first_indexed 2024-12-12T23:33:41Z
format Article
id doaj.art-9350acd99daf42f89264329686bfdff5
institution Directory Open Access Journal
issn 2405-8440
language English
last_indexed 2024-12-12T23:33:41Z
publishDate 2018-08-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj.art-9350acd99daf42f89264329686bfdff52022-12-22T00:07:38ZengElsevierHeliyon2405-84402018-08-0148e00752Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometryHiroyuki Masaki0Shinji Yasuike1Kenji Matsumoto2Masaru Tajiri3Yoshihiro Yoshioka4Seiji Inoba5Environmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, Japan; Corresponding author.Environmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanEnvironmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, JapanCoal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to management and/or screening their leachability. However, satisfactory methods to measure boron alone have not been reported. In this study, we developed an instrument for the non-contact analysis of boron in CFA samples. This simple instrument consisted of a sealed neutron source, a moderator, a proportional counter, and a signal processing device. The analysis method, based on thermal neutron absorptiometry, can rapidly measure the boron content within five minutes without pre-treatment. We applied the developed equipment to over 200 CFA samples, and excellent correlation was obtained between the proposed and traditional methods. These results indicated that the developed equipment is useful for managing and/or screening boron in CFA.http://www.sciencedirect.com/science/article/pii/S2405844018317778Analytical chemistryCivil engineeringEnvironmental scienceIndustrial engineering
spellingShingle Hiroyuki Masaki
Shinji Yasuike
Kenji Matsumoto
Masaru Tajiri
Yoshihiro Yoshioka
Seiji Inoba
Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
Heliyon
Analytical chemistry
Civil engineering
Environmental science
Industrial engineering
title Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
title_full Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
title_fullStr Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
title_full_unstemmed Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
title_short Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
title_sort development of a novel non contact and quick response detector for boron in coal fly ash based on thermal neutron absorptiometry
topic Analytical chemistry
Civil engineering
Environmental science
Industrial engineering
url http://www.sciencedirect.com/science/article/pii/S2405844018317778
work_keys_str_mv AT hiroyukimasaki developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry
AT shinjiyasuike developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry
AT kenjimatsumoto developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry
AT masarutajiri developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry
AT yoshihiroyoshioka developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry
AT seijiinoba developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry