Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry
Coal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to managem...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2018-08-01
|
Series: | Heliyon |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844018317778 |
_version_ | 1818279460775919616 |
---|---|
author | Hiroyuki Masaki Shinji Yasuike Kenji Matsumoto Masaru Tajiri Yoshihiro Yoshioka Seiji Inoba |
author_facet | Hiroyuki Masaki Shinji Yasuike Kenji Matsumoto Masaru Tajiri Yoshihiro Yoshioka Seiji Inoba |
author_sort | Hiroyuki Masaki |
collection | DOAJ |
description | Coal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to management and/or screening their leachability. However, satisfactory methods to measure boron alone have not been reported. In this study, we developed an instrument for the non-contact analysis of boron in CFA samples. This simple instrument consisted of a sealed neutron source, a moderator, a proportional counter, and a signal processing device. The analysis method, based on thermal neutron absorptiometry, can rapidly measure the boron content within five minutes without pre-treatment. We applied the developed equipment to over 200 CFA samples, and excellent correlation was obtained between the proposed and traditional methods. These results indicated that the developed equipment is useful for managing and/or screening boron in CFA. |
first_indexed | 2024-12-12T23:33:41Z |
format | Article |
id | doaj.art-9350acd99daf42f89264329686bfdff5 |
institution | Directory Open Access Journal |
issn | 2405-8440 |
language | English |
last_indexed | 2024-12-12T23:33:41Z |
publishDate | 2018-08-01 |
publisher | Elsevier |
record_format | Article |
series | Heliyon |
spelling | doaj.art-9350acd99daf42f89264329686bfdff52022-12-22T00:07:38ZengElsevierHeliyon2405-84402018-08-0148e00752Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometryHiroyuki Masaki0Shinji Yasuike1Kenji Matsumoto2Masaru Tajiri3Yoshihiro Yoshioka4Seiji Inoba5Environmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, Japan; Corresponding author.Environmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanShinko Engineering & Maintenance Co., Ltd., 4-5-22, Iwayakitamachi, Nada-ku Kobe-shi, Hyogo 657-0846, JapanEnvironmental Science Research Laboratory, Central Research Institute of Electric Power Industry, 1646 Abiko, Abiko–shi, Chiba 270–1194, JapanCoal fly ash (CFA), a by-product from coal-fired power plants, has many applications. However, there are concerns that the trace elements in CFA-based materials may contaminate groundwater. Therefore, many methods have been developed to rapidly measure these trace elements in CFA in order to management and/or screening their leachability. However, satisfactory methods to measure boron alone have not been reported. In this study, we developed an instrument for the non-contact analysis of boron in CFA samples. This simple instrument consisted of a sealed neutron source, a moderator, a proportional counter, and a signal processing device. The analysis method, based on thermal neutron absorptiometry, can rapidly measure the boron content within five minutes without pre-treatment. We applied the developed equipment to over 200 CFA samples, and excellent correlation was obtained between the proposed and traditional methods. These results indicated that the developed equipment is useful for managing and/or screening boron in CFA.http://www.sciencedirect.com/science/article/pii/S2405844018317778Analytical chemistryCivil engineeringEnvironmental scienceIndustrial engineering |
spellingShingle | Hiroyuki Masaki Shinji Yasuike Kenji Matsumoto Masaru Tajiri Yoshihiro Yoshioka Seiji Inoba Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry Heliyon Analytical chemistry Civil engineering Environmental science Industrial engineering |
title | Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry |
title_full | Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry |
title_fullStr | Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry |
title_full_unstemmed | Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry |
title_short | Development of a novel non-contact and quick-response detector for boron in coal fly ash based on thermal neutron absorptiometry |
title_sort | development of a novel non contact and quick response detector for boron in coal fly ash based on thermal neutron absorptiometry |
topic | Analytical chemistry Civil engineering Environmental science Industrial engineering |
url | http://www.sciencedirect.com/science/article/pii/S2405844018317778 |
work_keys_str_mv | AT hiroyukimasaki developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry AT shinjiyasuike developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry AT kenjimatsumoto developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry AT masarutajiri developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry AT yoshihiroyoshioka developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry AT seijiinoba developmentofanovelnoncontactandquickresponsedetectorforboronincoalflyashbasedonthermalneutronabsorptiometry |