8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate
In the title compound, C18H16N2O5S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.078 (1) Å (r.m.s. deviation = 0.046 Å). The dihedral angle between the coumarin ring system and the toluene ri...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810054620 |
| _version_ | 1818906307924590592 |
|---|---|
| author | H. Yuvaraj D. Gayathri Rajesh G. Kalkhambkar G. M. Kulkarni Rajendra M. Bapset |
| author_facet | H. Yuvaraj D. Gayathri Rajesh G. Kalkhambkar G. M. Kulkarni Rajendra M. Bapset |
| author_sort | H. Yuvaraj |
| collection | DOAJ |
| description | In the title compound, C18H16N2O5S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.078 (1) Å (r.m.s. deviation = 0.046 Å). The dihedral angle between the coumarin ring system and the toluene ring (r.m.s. deviation = 0.004 Å) is 2.77 (1)°. The crystal packing is stabilized by C—H...O and N—H...O intermolecular hydrogen bonds generating C(8), C(9) and C(11) chains and R22(14), R22(23) and R43(13) ring graph sets. |
| first_indexed | 2024-12-19T21:37:09Z |
| format | Article |
| id | doaj.art-935aa5b222844c64b06fcb4bf95e7a70 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:37:09Z |
| publishDate | 2011-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-935aa5b222844c64b06fcb4bf95e7a702022-12-21T20:04:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672o323o32310.1107/S16005368100546208-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonateH. YuvarajD. GayathriRajesh G. KalkhambkarG. M. KulkarniRajendra M. BapsetIn the title compound, C18H16N2O5S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.078 (1) Å (r.m.s. deviation = 0.046 Å). The dihedral angle between the coumarin ring system and the toluene ring (r.m.s. deviation = 0.004 Å) is 2.77 (1)°. The crystal packing is stabilized by C—H...O and N—H...O intermolecular hydrogen bonds generating C(8), C(9) and C(11) chains and R22(14), R22(23) and R43(13) ring graph sets.http://scripts.iucr.org/cgi-bin/paper?S1600536810054620 |
| spellingShingle | H. Yuvaraj D. Gayathri Rajesh G. Kalkhambkar G. M. Kulkarni Rajendra M. Bapset 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate Acta Crystallographica Section E |
| title | 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate |
| title_full | 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate |
| title_fullStr | 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate |
| title_full_unstemmed | 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate |
| title_short | 8-[(Hydrazinylidene)methyl]-4-methyl-2-oxo-2H-chromen-7-yl 4-methylbenzenesulfonate |
| title_sort | 8 hydrazinylidene methyl 4 methyl 2 oxo 2h chromen 7 yl 4 methylbenzenesulfonate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810054620 |
| work_keys_str_mv | AT hyuvaraj 8hydrazinylidenemethyl4methyl2oxo2hchromen7yl4methylbenzenesulfonate AT dgayathri 8hydrazinylidenemethyl4methyl2oxo2hchromen7yl4methylbenzenesulfonate AT rajeshgkalkhambkar 8hydrazinylidenemethyl4methyl2oxo2hchromen7yl4methylbenzenesulfonate AT gmkulkarni 8hydrazinylidenemethyl4methyl2oxo2hchromen7yl4methylbenzenesulfonate AT rajendrambapset 8hydrazinylidenemethyl4methyl2oxo2hchromen7yl4methylbenzenesulfonate |