Chloridobis[diphenylglyoximato(1–)-κ2N,N′](1H-imidazole-κN3)cobalt(III) hemihydrate
The Co centre in the title compound, [Co(C14H11N2O2)2Cl(C3H4N2)]·0.5H2O, shows a slightly distorted octahedral coordination geometry. The glyoximate units of the molecule are linked by O—H...O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal pack...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680804347X |
| Summary: | The Co centre in the title compound, [Co(C14H11N2O2)2Cl(C3H4N2)]·0.5H2O, shows a slightly distorted octahedral coordination geometry. The glyoximate units of the molecule are linked by O—H...O hydrogen bonds with the H atom almost in the middle of the two O atoms. The crystal packing is stabilized through intermolecular N—H...O, N—H...N and O—H...Cl hydrogen bonds. The uncoordinated water molecule shows half-occupation. |
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| ISSN: | 1600-5368 |