Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation
Olefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2016-04-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms11129 |
| _version_ | 1819122505957244928 |
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| author | Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu |
| author_facet | Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu |
| author_sort | Xi Lu |
| collection | DOAJ |
| description | Olefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope. |
| first_indexed | 2024-12-22T06:53:32Z |
| format | Article |
| id | doaj.art-93b07284e1f74b9ba0ea3f6d17171499 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-22T06:53:32Z |
| publishDate | 2016-04-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-93b07284e1f74b9ba0ea3f6d171714992022-12-21T18:35:03ZengNature PortfolioNature Communications2041-17232016-04-01711810.1038/ncomms11129Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonationXi Lu0Bin Xiao1Zhenqi Zhang2Tianjun Gong3Wei Su4Jun Yi5Yao Fu6Lei Liu7Hefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, University of Science and Technology of ChinaDepartment of Chemistry, Tsinghua UniversityOlefins are employed in many coupling procedures but direct hydrocarbonations of unactivated olefins remain to be developed. Here, the authors report the nickel-catalyzed reductive coupling of olefins with aryl and alky electrophiles under mild conditions and with a broad substrate scope.https://doi.org/10.1038/ncomms11129 |
| spellingShingle | Xi Lu Bin Xiao Zhenqi Zhang Tianjun Gong Wei Su Jun Yi Yao Fu Lei Liu Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation Nature Communications |
| title | Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
| title_full | Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
| title_fullStr | Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
| title_full_unstemmed | Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
| title_short | Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation |
| title_sort | practical carbon carbon bond formation from olefins through nickel catalyzed reductive olefin hydrocarbonation |
| url | https://doi.org/10.1038/ncomms11129 |
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