Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]
The solvothermal reaction of H3BO3, KCF3SO3, Mg(CF3SO3)2 and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK0.5[B6O10](OH)0.5·0.5H2O. Its structure features an intricate three-dimensional framework built from [B6O13]8− clusters, thus resulting in a six-connected achiral net with h...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2022-10-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989022008982 |
| _version_ | 1828196490441392128 |
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| author | Qi-Ming Qiu Jian-Biao Song |
| author_facet | Qi-Ming Qiu Jian-Biao Song |
| author_sort | Qi-Ming Qiu |
| collection | DOAJ |
| description | The solvothermal reaction of H3BO3, KCF3SO3, Mg(CF3SO3)2 and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK0.5[B6O10](OH)0.5·0.5H2O. Its structure features an intricate three-dimensional framework built from [B6O13]8− clusters, thus resulting in a six-connected achiral net with high symmetry. Each [B6O13]8− building block is composed of three trigonal BO3 and three tetrahedral BO4 units, with these BO4 units being further connected to neighboring BO3 units, giving rise to an oxoboron cluster of the general formula [B6O10]2−. |
| first_indexed | 2024-04-12T10:03:20Z |
| format | Article |
| id | doaj.art-93b3b0c9f7214906abb1278fff10367e |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-04-12T10:03:20Z |
| publishDate | 2022-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-93b3b0c9f7214906abb1278fff10367e2022-12-22T03:37:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902022-10-0178101003100510.1107/S2056989022008982tx2057Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]Qi-Ming Qiu0Jian-Biao Song1School of Science, China University of Geosciences, Beijing 100083, People's Republic of ChinaBeijing Chaoyang Foreign Language School, Beijing 100101, People's Republic of ChinaThe solvothermal reaction of H3BO3, KCF3SO3, Mg(CF3SO3)2 and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK0.5[B6O10](OH)0.5·0.5H2O. Its structure features an intricate three-dimensional framework built from [B6O13]8− clusters, thus resulting in a six-connected achiral net with high symmetry. Each [B6O13]8− building block is composed of three trigonal BO3 and three tetrahedral BO4 units, with these BO4 units being further connected to neighboring BO3 units, giving rise to an oxoboron cluster of the general formula [B6O10]2−.http://scripts.iucr.org/cgi-bin/paper?S2056989022008982alkali–earth-metal boratealkaline-earth-metal boratesolvothermal synthesisthree-dimensional frameworkcrystal structure |
| spellingShingle | Qi-Ming Qiu Jian-Biao Song Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] Acta Crystallographica Section E: Crystallographic Communications alkali–earth-metal borate alkaline-earth-metal borate solvothermal synthesis three-dimensional framework crystal structure |
| title | Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] |
| title_full | Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] |
| title_fullStr | Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] |
| title_full_unstemmed | Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] |
| title_short | Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate] |
| title_sort | crystal structure of mgk0 5 b6o10 oh 0 5·0 5h2o poly dimagnesium potassium bis hexaborate hydroxide monohydrate |
| topic | alkali–earth-metal borate alkaline-earth-metal borate solvothermal synthesis three-dimensional framework crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989022008982 |
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