Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate
The title complex, [Ag(C18H15P)4]BF4, was prepared by the reaction of silver(I) tetrafluoridoborate and triphenylphosphane in the presence of 1,2-bis(pyridin-2-yl)ethylene. The AgI atom is tetrahedrally coordinated by four P atoms from triphenylphosphane (PPh3) ligands. Due to symmetry, the tetraflu...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812018247 |
| _version_ | 1818500248208670720 |
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| author | Qi-Ming Qiu Xin Wang Qiong-Hua Jin Xu Huang Cun-Lin Zhang |
| author_facet | Qi-Ming Qiu Xin Wang Qiong-Hua Jin Xu Huang Cun-Lin Zhang |
| author_sort | Qi-Ming Qiu |
| collection | DOAJ |
| description | The title complex, [Ag(C18H15P)4]BF4, was prepared by the reaction of silver(I) tetrafluoridoborate and triphenylphosphane in the presence of 1,2-bis(pyridin-2-yl)ethylene. The AgI atom is tetrahedrally coordinated by four P atoms from triphenylphosphane (PPh3) ligands. Due to symmetry, the tetrafluoridoborate anion is disordered over three positions (each with one third occupancy). The tetrafluoridoborate anion does not coordinate to the AgI atom. |
| first_indexed | 2024-12-10T20:40:11Z |
| format | Article |
| id | doaj.art-93ba17b6bd5249d6b5930770977be2b9 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T20:40:11Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-93ba17b6bd5249d6b5930770977be2b92022-12-22T01:34:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m706m70610.1107/S1600536812018247Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborateQi-Ming QiuXin WangQiong-Hua JinXu HuangCun-Lin ZhangThe title complex, [Ag(C18H15P)4]BF4, was prepared by the reaction of silver(I) tetrafluoridoborate and triphenylphosphane in the presence of 1,2-bis(pyridin-2-yl)ethylene. The AgI atom is tetrahedrally coordinated by four P atoms from triphenylphosphane (PPh3) ligands. Due to symmetry, the tetrafluoridoborate anion is disordered over three positions (each with one third occupancy). The tetrafluoridoborate anion does not coordinate to the AgI atom.http://scripts.iucr.org/cgi-bin/paper?S1600536812018247 |
| spellingShingle | Qi-Ming Qiu Xin Wang Qiong-Hua Jin Xu Huang Cun-Lin Zhang Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate Acta Crystallographica Section E |
| title | Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate |
| title_full | Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate |
| title_fullStr | Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate |
| title_full_unstemmed | Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate |
| title_short | Tetrakis(triphenylphosphane-κP)silver(I) tetrafluoridoborate |
| title_sort | tetrakis triphenylphosphane amp 954 p silver i tetrafluoridoborate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812018247 |
| work_keys_str_mv | AT qimingqiu tetrakistriphenylphosphaneamp954psilveritetrafluoridoborate AT xinwang tetrakistriphenylphosphaneamp954psilveritetrafluoridoborate AT qionghuajin tetrakistriphenylphosphaneamp954psilveritetrafluoridoborate AT xuhuang tetrakistriphenylphosphaneamp954psilveritetrafluoridoborate AT cunlinzhang tetrakistriphenylphosphaneamp954psilveritetrafluoridoborate |