Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide
The title compound, C20H19NO2, is of interest as a precursor to biologically active substituted quinolines and related compounds. This compound crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angles between mean planes of the methylphenyl ring and the napht...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2018-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018008423 |
| _version_ | 1818321327582347264 |
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| author | Khawla Boudebbous Wissem Zemamouche Abdelmadjid Debache Noudjoud Hamdouni Ali Boudjada |
| author_facet | Khawla Boudebbous Wissem Zemamouche Abdelmadjid Debache Noudjoud Hamdouni Ali Boudjada |
| author_sort | Khawla Boudebbous |
| collection | DOAJ |
| description | The title compound, C20H19NO2, is of interest as a precursor to biologically active substituted quinolines and related compounds. This compound crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angles between mean planes of the methylphenyl ring and the naphthalene ring system are 78.32 (6) and 84.70 (6)° in molecules A and B, respectively. In the crystal, the antiferroelectric packing of molecules A and B is of an ABBAABB type along the b-axis direction. The crystal structure features N—H...O, O—H...O and weak C—H...O hydrogen bonds, which link the molecules into infinite chains propagating along the b-axis direction. |
| first_indexed | 2024-12-13T10:39:09Z |
| format | Article |
| id | doaj.art-93c46ed829d0405c96c622b952adc597 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:39:09Z |
| publishDate | 2018-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-93c46ed829d0405c96c622b952adc5972022-12-21T23:50:36ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-07-017471002100510.1107/S2056989018008423xu5928Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamideKhawla Boudebbous0Wissem Zemamouche1Abdelmadjid Debache2Noudjoud Hamdouni3Ali Boudjada4Laboratoire de Synthèse de Molécules, d'Intérêts Biologiques, Département de Chimie, Université Mentouri-Constantine, 25000 Constantine, AlgeriaLaboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, AlgeriaLaboratoire de Synthèse de Molécules, d'Intérêts Biologiques, Département de Chimie, Université Mentouri-Constantine, 25000 Constantine, AlgeriaLaboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, AlgeriaLaboratoire de Cristallographie, Département de Physique, Université Mentouri-Constantine, 25000 Constantine, AlgeriaThe title compound, C20H19NO2, is of interest as a precursor to biologically active substituted quinolines and related compounds. This compound crystallizes with two independent molecules (A and B) in the asymmetric unit. The dihedral angles between mean planes of the methylphenyl ring and the naphthalene ring system are 78.32 (6) and 84.70 (6)° in molecules A and B, respectively. In the crystal, the antiferroelectric packing of molecules A and B is of an ABBAABB type along the b-axis direction. The crystal structure features N—H...O, O—H...O and weak C—H...O hydrogen bonds, which link the molecules into infinite chains propagating along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S20569890180084231-aminoalkyl-2-naphtholscrystal structurehydrogen bondingHirshfeld surface |
| spellingShingle | Khawla Boudebbous Wissem Zemamouche Abdelmadjid Debache Noudjoud Hamdouni Ali Boudjada Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide Acta Crystallographica Section E: Crystallographic Communications 1-aminoalkyl-2-naphthols crystal structure hydrogen bonding Hirshfeld surface |
| title | Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide |
| title_full | Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide |
| title_short | Crystal structure and Hirshfeld surface analysis of N-[(2-hydroxynaphthalen-1-yl)(3-methylphenyl)methyl]acetamide |
| title_sort | crystal structure and hirshfeld surface analysis of n 2 hydroxynaphthalen 1 yl 3 methylphenyl methyl acetamide |
| topic | 1-aminoalkyl-2-naphthols crystal structure hydrogen bonding Hirshfeld surface |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989018008423 |
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