Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings

A new kind of crosslinkable potato starch-based graft copolymer emulsion (PoSt-g-BMD) has been prepared using butyl acrylate (BA) and methyl methacrylate (MMA) as main monomers, and diacetone acrylamide (DAAM) as functional monomer. The keto-carbonyl group of DAAM in PoSt-g-BMD copolymer could react...

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Main Authors: Rong-Min Wang, Xiao-Wen Wang, Jun-Feng Guo, Yu-Feng He, Meng-Lan Jiang
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2013-07-01
Series:Materials Research
Subjects:
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000600005&tlng=en
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author Rong-Min Wang
Xiao-Wen Wang
Jun-Feng Guo
Yu-Feng He
Meng-Lan Jiang
author_facet Rong-Min Wang
Xiao-Wen Wang
Jun-Feng Guo
Yu-Feng He
Meng-Lan Jiang
author_sort Rong-Min Wang
collection DOAJ
description A new kind of crosslinkable potato starch-based graft copolymer emulsion (PoSt-g-BMD) has been prepared using butyl acrylate (BA) and methyl methacrylate (MMA) as main monomers, and diacetone acrylamide (DAAM) as functional monomer. The keto-carbonyl group of DAAM in PoSt-g-BMD copolymer could react with adipic dihydrazide (ADH) at ambient temperature to form cross-linked copolymer. The PoSt-g-BMD had been characterized by the FT-IR spectra and thermogravimetric analysis (TGA). It was applied to prepare the humidity-controlling coatings (PoSt-g-BMD-C). The water absorption of PoSt-g-BMD-C was 105%. The humidity controlling properties were also measured, and the PoSt-g-BMD-C exhibited humidity sensitivity and humidity retention because fillers of porous structure combined with PoSt-g-BMD copolymer emulsion based on scanning electron microscopy images (SEM). It could be widely applied in indoor coating for controlling humidity.
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spelling doaj.art-93d69c4797634be99096b9f3f62488fc2022-12-21T17:42:40ZengAssociação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol)Materials Research1516-14392013-07-011661246125310.1590/S1516-14392013005000117Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatingsRong-Min Wang0Xiao-Wen Wang1Jun-Feng Guo2Yu-Feng He3Meng-Lan Jiang4Northwest Normal UniversityNorthwest Normal UniversityNorthwest Normal UniversityNorthwest Normal UniversityNorthwest Normal UniversityA new kind of crosslinkable potato starch-based graft copolymer emulsion (PoSt-g-BMD) has been prepared using butyl acrylate (BA) and methyl methacrylate (MMA) as main monomers, and diacetone acrylamide (DAAM) as functional monomer. The keto-carbonyl group of DAAM in PoSt-g-BMD copolymer could react with adipic dihydrazide (ADH) at ambient temperature to form cross-linked copolymer. The PoSt-g-BMD had been characterized by the FT-IR spectra and thermogravimetric analysis (TGA). It was applied to prepare the humidity-controlling coatings (PoSt-g-BMD-C). The water absorption of PoSt-g-BMD-C was 105%. The humidity controlling properties were also measured, and the PoSt-g-BMD-C exhibited humidity sensitivity and humidity retention because fillers of porous structure combined with PoSt-g-BMD copolymer emulsion based on scanning electron microscopy images (SEM). It could be widely applied in indoor coating for controlling humidity.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000600005&tlng=enpotato starch-based copolymerambient cross-linked copolymergraft copolymerizationhumidity-controlling coating
spellingShingle Rong-Min Wang
Xiao-Wen Wang
Jun-Feng Guo
Yu-Feng He
Meng-Lan Jiang
Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
Materials Research
potato starch-based copolymer
ambient cross-linked copolymer
graft copolymerization
humidity-controlling coating
title Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
title_full Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
title_fullStr Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
title_full_unstemmed Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
title_short Crosslinkable potato starch-based graft copolymer emulsion for humidity controlling coatings
title_sort crosslinkable potato starch based graft copolymer emulsion for humidity controlling coatings
topic potato starch-based copolymer
ambient cross-linked copolymer
graft copolymerization
humidity-controlling coating
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392013000600005&tlng=en
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AT junfengguo crosslinkablepotatostarchbasedgraftcopolymeremulsionforhumiditycontrollingcoatings
AT yufenghe crosslinkablepotatostarchbasedgraftcopolymeremulsionforhumiditycontrollingcoatings
AT menglanjiang crosslinkablepotatostarchbasedgraftcopolymeremulsionforhumiditycontrollingcoatings