Selective Dendritic Fluorescent Sensors for Zn(II)
A series of dendritic 8-hydroxyquinoline (8-HQ) and 5-dialkyl(aryl)aminomethyl-8-HQ derivatives were synthesized and their fluoroionophoric properties towardrepresentative alkali, alkaline earth, group IIIA and transition metal ions wereinvestigated. Among the selected ions, Zn(II) enhanced th...
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MDPI AG
2008-04-01
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Series: | Molecules |
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Online Access: | http://www.mdpi.com/1420-3049/13/4/922/ |
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author | Yaowu Sha Ruogu Peng Feng Wang |
author_facet | Yaowu Sha Ruogu Peng Feng Wang |
author_sort | Yaowu Sha |
collection | DOAJ |
description | A series of dendritic 8-hydroxyquinoline (8-HQ) and 5-dialkyl(aryl)aminomethyl-8-HQ derivatives were synthesized and their fluoroionophoric properties towardrepresentative alkali, alkaline earth, group IIIA and transition metal ions wereinvestigated. Among the selected ions, Zn(II) enhanced the fluorescence of N-di-(methoxycarbonylethyl)aminoethyl-3-[4-(8-hydroxyquinolin-5-ylmethyl)piperazin-1-yl]-propanoic amide] (7) by 31-fold, while Al(III) caused enhancement to some extent. Theabsence of any significant fluorescence enhancement by the other ions examined renders 7a highly useful Zn(II)-selective fluorescent sensor. |
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format | Article |
id | doaj.art-93fc7e4d202848859ebf8464d75ed787 |
institution | Directory Open Access Journal |
issn | 1420-3049 |
language | English |
last_indexed | 2024-04-12T20:56:01Z |
publishDate | 2008-04-01 |
publisher | MDPI AG |
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series | Molecules |
spelling | doaj.art-93fc7e4d202848859ebf8464d75ed7872022-12-22T03:16:59ZengMDPI AGMolecules1420-30492008-04-0113492293010.3390/molecules13040922Selective Dendritic Fluorescent Sensors for Zn(II)Yaowu ShaRuogu PengFeng WangA series of dendritic 8-hydroxyquinoline (8-HQ) and 5-dialkyl(aryl)aminomethyl-8-HQ derivatives were synthesized and their fluoroionophoric properties towardrepresentative alkali, alkaline earth, group IIIA and transition metal ions wereinvestigated. Among the selected ions, Zn(II) enhanced the fluorescence of N-di-(methoxycarbonylethyl)aminoethyl-3-[4-(8-hydroxyquinolin-5-ylmethyl)piperazin-1-yl]-propanoic amide] (7) by 31-fold, while Al(III) caused enhancement to some extent. Theabsence of any significant fluorescence enhancement by the other ions examined renders 7a highly useful Zn(II)-selective fluorescent sensor.http://www.mdpi.com/1420-3049/13/4/922/Dendritic8-hydroxyquinolineZn2+fluorescence enhancement. |
spellingShingle | Yaowu Sha Ruogu Peng Feng Wang Selective Dendritic Fluorescent Sensors for Zn(II) Molecules Dendritic 8-hydroxyquinoline Zn2+ fluorescence enhancement. |
title | Selective Dendritic Fluorescent Sensors for Zn(II) |
title_full | Selective Dendritic Fluorescent Sensors for Zn(II) |
title_fullStr | Selective Dendritic Fluorescent Sensors for Zn(II) |
title_full_unstemmed | Selective Dendritic Fluorescent Sensors for Zn(II) |
title_short | Selective Dendritic Fluorescent Sensors for Zn(II) |
title_sort | selective dendritic fluorescent sensors for zn ii |
topic | Dendritic 8-hydroxyquinoline Zn2+ fluorescence enhancement. |
url | http://www.mdpi.com/1420-3049/13/4/922/ |
work_keys_str_mv | AT yaowusha selectivedendriticfluorescentsensorsforznii AT ruogupeng selectivedendriticfluorescentsensorsforznii AT fengwang selectivedendriticfluorescentsensorsforznii |