Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds
A two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>]·4-dpds (<b>1</b>) (4-dpds = 4,4′-dipyridyldusulfide and bdc<sup>2−</sup> = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined...
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MDPI AG
2020-05-01
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| author | Chih-Chieh Wang Zi-Ling Huang Yueh-Yi Tseng Gia-Bin Sheu Shih-I Lu Gene-Hsiang Lee Hwo-Shuenn Sheu |
| author_facet | Chih-Chieh Wang Zi-Ling Huang Yueh-Yi Tseng Gia-Bin Sheu Shih-I Lu Gene-Hsiang Lee Hwo-Shuenn Sheu |
| author_sort | Chih-Chieh Wang |
| collection | DOAJ |
| description | A two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>]·4-dpds (<b>1</b>) (4-dpds = 4,4′-dipyridyldusulfide and bdc<sup>2−</sup> = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined by single-crystal X-ray diffractometer. In <b>1</b>, the bdc<sup>2−</sup> and 4-dpds both act as bridging ligands connecting the Co(II) ions to form a 2D wrinkled-like layered coordination polymer. Two wrinkled-like layered coordination polymers are mutually penetrated to generate a doubly interpenetrated framework, and then extended to its 3D architecture via the supramolecular forces between doubly interpenetrated 2D frameworks and free 4-dpds ligands by intermolecular O–H⋅⋅⋅N hydrogen bonding interaction. Crystal packing arrangements were characterized by fingerprint plots, which were derived from the Hirshfeld Surfaces analysis, and showed that intermolecular hydrogen bonding interactions are the most important interactions on the construction of the crystal <b>1</b>. |
| first_indexed | 2024-03-10T19:37:50Z |
| format | Article |
| id | doaj.art-93fe95974de24d8dbed1ef8d9bf356f2 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-10T19:37:50Z |
| publishDate | 2020-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-93fe95974de24d8dbed1ef8d9bf356f22023-11-20T01:34:20ZengMDPI AGCrystals2073-43522020-05-0110541910.3390/cryst10050419Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpdsChih-Chieh Wang0Zi-Ling Huang1Yueh-Yi Tseng2Gia-Bin Sheu3Shih-I Lu4Gene-Hsiang Lee5Hwo-Shuenn Sheu6Department of Chemistry, Soochow University, Taipei 11102, TaiwanDepartment of Chemistry, Soochow University, Taipei 11102, TaiwanDepartment of Chemistry, Soochow University, Taipei 11102, TaiwanDepartment of Chemistry, Soochow University, Taipei 11102, TaiwanDepartment of Chemistry, Soochow University, Taipei 11102, TaiwanInstrumentation Center, National Taiwan University, Taipei 10617, TaiwanNational Synchrotron Radiation Research Center, Hsinchu 30076, TaiwanA two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>]·4-dpds (<b>1</b>) (4-dpds = 4,4′-dipyridyldusulfide and bdc<sup>2−</sup> = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined by single-crystal X-ray diffractometer. In <b>1</b>, the bdc<sup>2−</sup> and 4-dpds both act as bridging ligands connecting the Co(II) ions to form a 2D wrinkled-like layered coordination polymer. Two wrinkled-like layered coordination polymers are mutually penetrated to generate a doubly interpenetrated framework, and then extended to its 3D architecture via the supramolecular forces between doubly interpenetrated 2D frameworks and free 4-dpds ligands by intermolecular O–H⋅⋅⋅N hydrogen bonding interaction. Crystal packing arrangements were characterized by fingerprint plots, which were derived from the Hirshfeld Surfaces analysis, and showed that intermolecular hydrogen bonding interactions are the most important interactions on the construction of the crystal <b>1</b>.https://www.mdpi.com/2073-4352/10/5/419coordination polymermetal-organic frameworkHirshfeld surface analysishydrogen bondpi-pi interaction |
| spellingShingle | Chih-Chieh Wang Zi-Ling Huang Yueh-Yi Tseng Gia-Bin Sheu Shih-I Lu Gene-Hsiang Lee Hwo-Shuenn Sheu Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds Crystals coordination polymer metal-organic framework Hirshfeld surface analysis hydrogen bond pi-pi interaction |
| title | Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds |
| title_full | Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds |
| title_fullStr | Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds |
| title_full_unstemmed | Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds |
| title_short | Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H<sub>2</sub>O)<sub>2</sub>] 4-dpds |
| title_sort | synthesis structural characterization and hirshfeld surface analysis of a 2d coordination polymer co 4 dpds bdc h sub 2 sub o sub 2 sub 4 dpds |
| topic | coordination polymer metal-organic framework Hirshfeld surface analysis hydrogen bond pi-pi interaction |
| url | https://www.mdpi.com/2073-4352/10/5/419 |
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