Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex
A new four-coordinated high-spin Co(II) complex was synthesized through the reactions of Co(NSC)<sub>2</sub> with bathocuproine, by the diffusion method, resulting in an infinite one-dimension chain. Both static and dynamic magnetic properties were measured. The magnetic properties inves...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-02-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4352/10/2/87 |
| Summary: | A new four-coordinated high-spin Co(II) complex was synthesized through the reactions of Co(NSC)<sub>2</sub> with bathocuproine, by the diffusion method, resulting in an infinite one-dimension chain. Both static and dynamic magnetic properties were measured. The magnetic properties investigation shows that the single Co<sup>II</sup> ion properties dominate the magnetic behavior in the complex. Despite the presence of a four-coordinated single Co<sup>II</sup> ion, no SMM properties were exhibited by the complex. |
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| ISSN: | 2073-4352 |