Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex
A new four-coordinated high-spin Co(II) complex was synthesized through the reactions of Co(NSC)<sub>2</sub> with bathocuproine, by the diffusion method, resulting in an infinite one-dimension chain. Both static and dynamic magnetic properties were measured. The magnetic properties inves...
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| Format: | Article |
| Language: | English |
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MDPI AG
2020-02-01
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| Series: | Crystals |
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| Online Access: | https://www.mdpi.com/2073-4352/10/2/87 |
| _version_ | 1828113631438438400 |
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| author | Mohd. Muddassir You Song |
| author_facet | Mohd. Muddassir You Song |
| author_sort | Mohd. Muddassir |
| collection | DOAJ |
| description | A new four-coordinated high-spin Co(II) complex was synthesized through the reactions of Co(NSC)<sub>2</sub> with bathocuproine, by the diffusion method, resulting in an infinite one-dimension chain. Both static and dynamic magnetic properties were measured. The magnetic properties investigation shows that the single Co<sup>II</sup> ion properties dominate the magnetic behavior in the complex. Despite the presence of a four-coordinated single Co<sup>II</sup> ion, no SMM properties were exhibited by the complex. |
| first_indexed | 2024-04-11T12:11:49Z |
| format | Article |
| id | doaj.art-94338e090187413db745f228b8c25d31 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T12:11:49Z |
| publishDate | 2020-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-94338e090187413db745f228b8c25d312022-12-22T04:24:36ZengMDPI AGCrystals2073-43522020-02-011028710.3390/cryst10020087cryst10020087Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) ComplexMohd. Muddassir0You Song1Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi ArabiaState Key Lab of Coordination Chemistry, Nanjing National Laboratory of Microstructures and School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, ChinaA new four-coordinated high-spin Co(II) complex was synthesized through the reactions of Co(NSC)<sub>2</sub> with bathocuproine, by the diffusion method, resulting in an infinite one-dimension chain. Both static and dynamic magnetic properties were measured. The magnetic properties investigation shows that the single Co<sup>II</sup> ion properties dominate the magnetic behavior in the complex. Despite the presence of a four-coordinated single Co<sup>II</sup> ion, no SMM properties were exhibited by the complex.https://www.mdpi.com/2073-4352/10/2/87x-ray crystallographycobalt complexh-bondingmagnetism |
| spellingShingle | Mohd. Muddassir You Song Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex Crystals x-ray crystallography cobalt complex h-bonding magnetism |
| title | Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex |
| title_full | Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex |
| title_fullStr | Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex |
| title_full_unstemmed | Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex |
| title_short | Synthesis, Crystal Structures and Magnetic Properties of Mononuclear High-Spin Cobalt(II) Complex |
| title_sort | synthesis crystal structures and magnetic properties of mononuclear high spin cobalt ii complex |
| topic | x-ray crystallography cobalt complex h-bonding magnetism |
| url | https://www.mdpi.com/2073-4352/10/2/87 |
| work_keys_str_mv | AT mohdmuddassir synthesiscrystalstructuresandmagneticpropertiesofmononuclearhighspincobaltiicomplex AT yousong synthesiscrystalstructuresandmagneticpropertiesofmononuclearhighspincobaltiicomplex |