LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
A highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge...
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Format: | Article |
Language: | English |
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Elsevier
2016-02-01
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Series: | Heliyon |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2405844015305806 |
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author | Daiwon Choi Xiaolin Li Wesley A. Henderson Qian Huang Satish K. Nune John P. Lemmon Vincent L. Sprenkle |
author_facet | Daiwon Choi Xiaolin Li Wesley A. Henderson Qian Huang Satish K. Nune John P. Lemmon Vincent L. Sprenkle |
author_sort | Daiwon Choi |
collection | DOAJ |
description | A highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge/discharge rate of C/10. The nanoplate precursor and final LiCoPO4/C cathode have been characterized using X-ray diffraction, thermogravimetric analysis − differential scanning calorimetry (TGA-DSC), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) and the electrochemical cycling stability has been investigated using different electrolytes, additives and separators. |
first_indexed | 2024-04-13T04:31:32Z |
format | Article |
id | doaj.art-943fd8b100e843f4877a580d54bc520e |
institution | Directory Open Access Journal |
issn | 2405-8440 |
language | English |
last_indexed | 2024-04-13T04:31:32Z |
publishDate | 2016-02-01 |
publisher | Elsevier |
record_format | Article |
series | Heliyon |
spelling | doaj.art-943fd8b100e843f4877a580d54bc520e2022-12-22T03:02:18ZengElsevierHeliyon2405-84402016-02-012210.1016/j.heliyon.2016.e00081LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteriesDaiwon ChoiXiaolin LiWesley A. HendersonQian HuangSatish K. NuneJohn P. LemmonVincent L. SprenkleA highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge/discharge rate of C/10. The nanoplate precursor and final LiCoPO4/C cathode have been characterized using X-ray diffraction, thermogravimetric analysis − differential scanning calorimetry (TGA-DSC), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) and the electrochemical cycling stability has been investigated using different electrolytes, additives and separators.http://www.sciencedirect.com/science/article/pii/S2405844015305806Materials scienceNanomaterialsMaterials synthesisMaterials chemistryAlternative energy technologies |
spellingShingle | Daiwon Choi Xiaolin Li Wesley A. Henderson Qian Huang Satish K. Nune John P. Lemmon Vincent L. Sprenkle LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries Heliyon Materials science Nanomaterials Materials synthesis Materials chemistry Alternative energy technologies |
title | LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries |
title_full | LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries |
title_fullStr | LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries |
title_full_unstemmed | LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries |
title_short | LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries |
title_sort | licopo4 cathode from a cohpo4·xh2o nanoplate precursor for high voltage li ion batteries |
topic | Materials science Nanomaterials Materials synthesis Materials chemistry Alternative energy technologies |
url | http://www.sciencedirect.com/science/article/pii/S2405844015305806 |
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