LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries

A highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge...

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Main Authors: Daiwon Choi, Xiaolin Li, Wesley A. Henderson, Qian Huang, Satish K. Nune, John P. Lemmon, Vincent L. Sprenkle
Format: Article
Language:English
Published: Elsevier 2016-02-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844015305806
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author Daiwon Choi
Xiaolin Li
Wesley A. Henderson
Qian Huang
Satish K. Nune
John P. Lemmon
Vincent L. Sprenkle
author_facet Daiwon Choi
Xiaolin Li
Wesley A. Henderson
Qian Huang
Satish K. Nune
John P. Lemmon
Vincent L. Sprenkle
author_sort Daiwon Choi
collection DOAJ
description A highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge/discharge rate of C/10. The nanoplate precursor and final LiCoPO4/C cathode have been characterized using X-ray diffraction, thermogravimetric analysis − differential scanning calorimetry (TGA-DSC), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) and the electrochemical cycling stability has been investigated using different electrolytes, additives and separators.
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spelling doaj.art-943fd8b100e843f4877a580d54bc520e2022-12-22T03:02:18ZengElsevierHeliyon2405-84402016-02-012210.1016/j.heliyon.2016.e00081LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteriesDaiwon ChoiXiaolin LiWesley A. HendersonQian HuangSatish K. NuneJohn P. LemmonVincent L. SprenkleA highly crystalline LiCoPO4/C cathode material has been synthesized without noticeable impurities via a single step solid-state reaction using CoHPO4·xH2O nanoplate as a precursor obtained by a simple precipitation route. The LiCoPO4/C cathode delivered a specific capacity of 125 mAhg−1 at a charge/discharge rate of C/10. The nanoplate precursor and final LiCoPO4/C cathode have been characterized using X-ray diffraction, thermogravimetric analysis − differential scanning calorimetry (TGA-DSC), transmission electron microscopy (TEM), and scanning electron microscopy (SEM) and the electrochemical cycling stability has been investigated using different electrolytes, additives and separators.http://www.sciencedirect.com/science/article/pii/S2405844015305806Materials scienceNanomaterialsMaterials synthesisMaterials chemistryAlternative energy technologies
spellingShingle Daiwon Choi
Xiaolin Li
Wesley A. Henderson
Qian Huang
Satish K. Nune
John P. Lemmon
Vincent L. Sprenkle
LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
Heliyon
Materials science
Nanomaterials
Materials synthesis
Materials chemistry
Alternative energy technologies
title LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
title_full LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
title_fullStr LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
title_full_unstemmed LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
title_short LiCoPO4 cathode from a CoHPO4·xH2O nanoplate precursor for high voltage Li-ion batteries
title_sort licopo4 cathode from a cohpo4·xh2o nanoplate precursor for high voltage li ion batteries
topic Materials science
Nanomaterials
Materials synthesis
Materials chemistry
Alternative energy technologies
url http://www.sciencedirect.com/science/article/pii/S2405844015305806
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