Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
Abstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Base...
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Format: | Article |
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Wiley-VCH
2023-09-01
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Series: | ChemElectroChem |
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Online Access: | https://doi.org/10.1002/celc.202300265 |
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author | Toni Kauppinen Petteri Laine Juho Välikangas Dr. Pekka Tynjälä Dr. Tao Hu Dr. Justin Salminen Prof. Ulla Lassi |
author_facet | Toni Kauppinen Petteri Laine Juho Välikangas Dr. Pekka Tynjälä Dr. Tao Hu Dr. Justin Salminen Prof. Ulla Lassi |
author_sort | Toni Kauppinen |
collection | DOAJ |
description | Abstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Based on the results, cationic impurities (Ca, Zn, Mg, and Fe) are co‐precipitated in the NMC811 precursors, as expected based on the thermodynamic considerations. The presence of these impurities was confirmed by several characterizations. Impurities did not affect the particle morphology or tap density of NMC811. Impurities had surprisingly minor effect on the cell performance. During the cycling, these cells provided good cyclability and high‐capacity retention after 1100 cycles compared to reference samples. |
first_indexed | 2024-03-12T11:23:16Z |
format | Article |
id | doaj.art-94598a1243164768be09d5f388cdb2c9 |
institution | Directory Open Access Journal |
issn | 2196-0216 |
language | English |
last_indexed | 2024-03-12T11:23:16Z |
publishDate | 2023-09-01 |
publisher | Wiley-VCH |
record_format | Article |
series | ChemElectroChem |
spelling | doaj.art-94598a1243164768be09d5f388cdb2c92023-09-01T13:22:37ZengWiley-VCHChemElectroChem2196-02162023-09-011017n/an/a10.1002/celc.202300265Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell PerformanceToni Kauppinen0Petteri Laine1Juho Välikangas2Dr. Pekka Tynjälä3Dr. Tao Hu4Dr. Justin Salminen5Prof. Ulla Lassi6University of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandBoliden Kokkola Sinkkiaukio 1 67100 Kokkola FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandAbstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Based on the results, cationic impurities (Ca, Zn, Mg, and Fe) are co‐precipitated in the NMC811 precursors, as expected based on the thermodynamic considerations. The presence of these impurities was confirmed by several characterizations. Impurities did not affect the particle morphology or tap density of NMC811. Impurities had surprisingly minor effect on the cell performance. During the cycling, these cells provided good cyclability and high‐capacity retention after 1100 cycles compared to reference samples.https://doi.org/10.1002/celc.202300265Anode sludgeCathode materialManganeseNCM811Residue |
spellingShingle | Toni Kauppinen Petteri Laine Juho Välikangas Dr. Pekka Tynjälä Dr. Tao Hu Dr. Justin Salminen Prof. Ulla Lassi Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance ChemElectroChem Anode sludge Cathode material Manganese NCM811 Residue |
title | Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance |
title_full | Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance |
title_fullStr | Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance |
title_full_unstemmed | Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance |
title_short | Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance |
title_sort | co precipitation of ncm 811 using recycled and purified manganese effect of impurities on the battery cell performance |
topic | Anode sludge Cathode material Manganese NCM811 Residue |
url | https://doi.org/10.1002/celc.202300265 |
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