Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance

Abstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Base...

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Main Authors: Toni Kauppinen, Petteri Laine, Juho Välikangas, Dr. Pekka Tynjälä, Dr. Tao Hu, Dr. Justin Salminen, Prof. Ulla Lassi
Format: Article
Language:English
Published: Wiley-VCH 2023-09-01
Series:ChemElectroChem
Subjects:
Online Access:https://doi.org/10.1002/celc.202300265
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author Toni Kauppinen
Petteri Laine
Juho Välikangas
Dr. Pekka Tynjälä
Dr. Tao Hu
Dr. Justin Salminen
Prof. Ulla Lassi
author_facet Toni Kauppinen
Petteri Laine
Juho Välikangas
Dr. Pekka Tynjälä
Dr. Tao Hu
Dr. Justin Salminen
Prof. Ulla Lassi
author_sort Toni Kauppinen
collection DOAJ
description Abstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Based on the results, cationic impurities (Ca, Zn, Mg, and Fe) are co‐precipitated in the NMC811 precursors, as expected based on the thermodynamic considerations. The presence of these impurities was confirmed by several characterizations. Impurities did not affect the particle morphology or tap density of NMC811. Impurities had surprisingly minor effect on the cell performance. During the cycling, these cells provided good cyclability and high‐capacity retention after 1100 cycles compared to reference samples.
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spelling doaj.art-94598a1243164768be09d5f388cdb2c92023-09-01T13:22:37ZengWiley-VCHChemElectroChem2196-02162023-09-011017n/an/a10.1002/celc.202300265Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell PerformanceToni Kauppinen0Petteri Laine1Juho Välikangas2Dr. Pekka Tynjälä3Dr. Tao Hu4Dr. Justin Salminen5Prof. Ulla Lassi6University of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandBoliden Kokkola Sinkkiaukio 1 67100 Kokkola FinlandUniversity of Oulu Research unit of Sustainable chemistry P.O.Box Oulu, 3000 90014 FinlandAbstract Co‐precipitation of NCM811 precursors and cathodes for lithium‐ion batteries was carried out using recycled and purified manganese solution. In this paper, the aim is to study the role of the impurities in the co‐precipitation step of NMC811 and further in the battery cell performance. Based on the results, cationic impurities (Ca, Zn, Mg, and Fe) are co‐precipitated in the NMC811 precursors, as expected based on the thermodynamic considerations. The presence of these impurities was confirmed by several characterizations. Impurities did not affect the particle morphology or tap density of NMC811. Impurities had surprisingly minor effect on the cell performance. During the cycling, these cells provided good cyclability and high‐capacity retention after 1100 cycles compared to reference samples.https://doi.org/10.1002/celc.202300265Anode sludgeCathode materialManganeseNCM811Residue
spellingShingle Toni Kauppinen
Petteri Laine
Juho Välikangas
Dr. Pekka Tynjälä
Dr. Tao Hu
Dr. Justin Salminen
Prof. Ulla Lassi
Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
ChemElectroChem
Anode sludge
Cathode material
Manganese
NCM811
Residue
title Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
title_full Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
title_fullStr Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
title_full_unstemmed Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
title_short Co‐precipitation of NCM 811 Using Recycled and Purified Manganese: Effect of Impurities on the Battery Cell Performance
title_sort co precipitation of ncm 811 using recycled and purified manganese effect of impurities on the battery cell performance
topic Anode sludge
Cathode material
Manganese
NCM811
Residue
url https://doi.org/10.1002/celc.202300265
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