Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone

Gas sensitive cerium oxide-tungsten oxide core-shell nanowires are synthesized and integrated directly into micromachined platforms via aerosol assisted chemical vapor deposition. Tests to various volatile organic compounds (acetone, ethanol, and toluene) involved in early disease diagnosis demonstr...

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Main Authors: Milena Tomić, Milena Šetka, Ondřej Chmela, Isabel Gràcia, Eduard Figueras, Carles Cané, Stella Vallejos
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Biosensors
Subjects:
Online Access:https://www.mdpi.com/2079-6374/8/4/116
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author Milena Tomić
Milena Šetka
Ondřej Chmela
Isabel Gràcia
Eduard Figueras
Carles Cané
Stella Vallejos
author_facet Milena Tomić
Milena Šetka
Ondřej Chmela
Isabel Gràcia
Eduard Figueras
Carles Cané
Stella Vallejos
author_sort Milena Tomić
collection DOAJ
description Gas sensitive cerium oxide-tungsten oxide core-shell nanowires are synthesized and integrated directly into micromachined platforms via aerosol assisted chemical vapor deposition. Tests to various volatile organic compounds (acetone, ethanol, and toluene) involved in early disease diagnosis demonstrate enhanced sensitivity to acetone for the core-shell structures in contrast to the non-modified materials (i.e., only tungsten oxide or cerium oxide). This is attributed to the high density of oxygen vacancy defects at the shell, as well as the formation of heterojunctions at the core-shell interface, which provide the modified nanowires with ‘extra’ chemical and electronic sensitization as compared to the non-modified materials.
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spelling doaj.art-945ef7cd70d2495faf20a15ad6370f7e2022-12-21T23:38:27ZengMDPI AGBiosensors2079-63742018-11-018411610.3390/bios8040116bios8040116Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to AcetoneMilena Tomić0Milena Šetka1Ondřej Chmela2Isabel Gràcia3Eduard Figueras4Carles Cané5Stella Vallejos6Instituto de Microelectrónica de Barcelona (IMB-CNM, CSIC), Campus UAB, 08193 Bellaterra, SpainCEITEC-Central European Institute of Technology, Brno University of Technology, 61200 Brno, Czech RepublicCEITEC-Central European Institute of Technology, Brno University of Technology, 61200 Brno, Czech RepublicInstituto de Microelectrónica de Barcelona (IMB-CNM, CSIC), Campus UAB, 08193 Bellaterra, SpainInstituto de Microelectrónica de Barcelona (IMB-CNM, CSIC), Campus UAB, 08193 Bellaterra, SpainInstituto de Microelectrónica de Barcelona (IMB-CNM, CSIC), Campus UAB, 08193 Bellaterra, SpainInstituto de Microelectrónica de Barcelona (IMB-CNM, CSIC), Campus UAB, 08193 Bellaterra, SpainGas sensitive cerium oxide-tungsten oxide core-shell nanowires are synthesized and integrated directly into micromachined platforms via aerosol assisted chemical vapor deposition. Tests to various volatile organic compounds (acetone, ethanol, and toluene) involved in early disease diagnosis demonstrate enhanced sensitivity to acetone for the core-shell structures in contrast to the non-modified materials (i.e., only tungsten oxide or cerium oxide). This is attributed to the high density of oxygen vacancy defects at the shell, as well as the formation of heterojunctions at the core-shell interface, which provide the modified nanowires with ‘extra’ chemical and electronic sensitization as compared to the non-modified materials.https://www.mdpi.com/2079-6374/8/4/116gas sensorsvolatile organic compounds (VOCs)acetonemetal oxidesheterojunctions
spellingShingle Milena Tomić
Milena Šetka
Ondřej Chmela
Isabel Gràcia
Eduard Figueras
Carles Cané
Stella Vallejos
Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
Biosensors
gas sensors
volatile organic compounds (VOCs)
acetone
metal oxides
heterojunctions
title Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
title_full Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
title_fullStr Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
title_full_unstemmed Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
title_short Cerium Oxide-Tungsten Oxide Core-Shell Nanowire-Based Microsensors Sensitive to Acetone
title_sort cerium oxide tungsten oxide core shell nanowire based microsensors sensitive to acetone
topic gas sensors
volatile organic compounds (VOCs)
acetone
metal oxides
heterojunctions
url https://www.mdpi.com/2079-6374/8/4/116
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AT ondrejchmela ceriumoxidetungstenoxidecoreshellnanowirebasedmicrosensorssensitivetoacetone
AT isabelgracia ceriumoxidetungstenoxidecoreshellnanowirebasedmicrosensorssensitivetoacetone
AT eduardfigueras ceriumoxidetungstenoxidecoreshellnanowirebasedmicrosensorssensitivetoacetone
AT carlescane ceriumoxidetungstenoxidecoreshellnanowirebasedmicrosensorssensitivetoacetone
AT stellavallejos ceriumoxidetungstenoxidecoreshellnanowirebasedmicrosensorssensitivetoacetone