Variable combinations of organophosphines in PtP3X derivatives: Structural aspects
This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There a...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2021-01-01
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| Series: | Main Group Metal Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/mgmc-2021-0003 |
| _version_ | 1818999634341658624 |
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| author | Melník Milan Mikuš Peter |
| author_facet | Melník Milan Mikuš Peter |
| author_sort | Melník Milan |
| collection | DOAJ |
| description | This review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There are variable combinations of organophosphines monodentate – P; bidentate- P,P; P,N; P,B; and tridentate – P,P,P; P,O,P; P,N,P; and P,S,P. The structural parameters (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about the Pt (II) atoms as well as of trans-influence. The sums of Pt–L (x4) bond distances growing with covalent radius of the X-atoms. |
| first_indexed | 2024-12-20T22:20:32Z |
| format | Article |
| id | doaj.art-94953dae5a9b496d9e070f61fe54457c |
| institution | Directory Open Access Journal |
| issn | 2191-0219 |
| language | English |
| last_indexed | 2024-12-20T22:20:32Z |
| publishDate | 2021-01-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Main Group Metal Chemistry |
| spelling | doaj.art-94953dae5a9b496d9e070f61fe54457c2022-12-21T19:24:57ZengDe GruyterMain Group Metal Chemistry2191-02192021-01-01441122110.1515/mgmc-2021-0003mgmc-2021-0003Variable combinations of organophosphines in PtP3X derivatives: Structural aspectsMelník Milan0Mikuš Peter1Comenius University in Bratislava, Faculty of Pharmacy, Department of Pharmaceutical Analysis and Nuclear Pharmacy, Odbojárov 10, SK-832 32Bratislava, Slovak RepublicComenius University in Bratislava, Faculty of Pharmacy, Department of Pharmaceutical Analysis and Nuclear Pharmacy, Odbojárov 10, SK-832 32Bratislava, Slovak Republic; Comenius University in Bratislava, Faculty of Pharmacy, Toxicological and Antidoping Center, Odbojárov 10, SK-832 32Bratislava, Slovak RepublicThis review covers over fifty Pt (II) complexes of the compositions PtP3X (X = H, OL, NL, BL, Cl, SL, Br, or I). These complexes crystallized in three crystal classes: monoclinic (23 examples) triclinic (17 examples) and orthorhombic (11 examples). The PtP3Cl is most common with 23 examples. There are variable combinations of organophosphines monodentate – P; bidentate- P,P; P,N; P,B; and tridentate – P,P,P; P,O,P; P,N,P; and P,S,P. The structural parameters (Pt–L, L–Pt–L) are analyzed and discussed with an attention to the distortion of a square-planar geometry about the Pt (II) atoms as well as of trans-influence. The sums of Pt–L (x4) bond distances growing with covalent radius of the X-atoms.https://doi.org/10.1515/mgmc-2021-0003structureorganophosphinesptp3xtrans-influence |
| spellingShingle | Melník Milan Mikuš Peter Variable combinations of organophosphines in PtP3X derivatives: Structural aspects Main Group Metal Chemistry structure organophosphines ptp3x trans-influence |
| title | Variable combinations of organophosphines in PtP3X derivatives: Structural aspects |
| title_full | Variable combinations of organophosphines in PtP3X derivatives: Structural aspects |
| title_fullStr | Variable combinations of organophosphines in PtP3X derivatives: Structural aspects |
| title_full_unstemmed | Variable combinations of organophosphines in PtP3X derivatives: Structural aspects |
| title_short | Variable combinations of organophosphines in PtP3X derivatives: Structural aspects |
| title_sort | variable combinations of organophosphines in ptp3x derivatives structural aspects |
| topic | structure organophosphines ptp3x trans-influence |
| url | https://doi.org/10.1515/mgmc-2021-0003 |
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