Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation

A high-performance Mg-10Gd-4Dy-1.5Ag-1Zn-0.5Zr (wt.%, EQ142X) alloy was designed by multi-element composite addition in this work, obtaining a high yield strength (~396 MPa) and ultimate tensile strength (~451 MPa) after hot extrusion and ageing. The high strength is mainly related to fine grains an...

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Main Authors: Jinshu Xie, Jinghuai Zhang, Shujuan Liu, Zihao You, Zhi Zhang, Tengfei Zhao, Xiaobo Zhang, Ruizhi Wu
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/13/7/1219
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author Jinshu Xie
Jinghuai Zhang
Shujuan Liu
Zihao You
Zhi Zhang
Tengfei Zhao
Xiaobo Zhang
Ruizhi Wu
author_facet Jinshu Xie
Jinghuai Zhang
Shujuan Liu
Zihao You
Zhi Zhang
Tengfei Zhao
Xiaobo Zhang
Ruizhi Wu
author_sort Jinshu Xie
collection DOAJ
description A high-performance Mg-10Gd-4Dy-1.5Ag-1Zn-0.5Zr (wt.%, EQ142X) alloy was designed by multi-element composite addition in this work, obtaining a high yield strength (~396 MPa) and ultimate tensile strength (~451 MPa) after hot extrusion and ageing. The high strength is mainly related to fine grains and nano-precipitates, especially the latter. <i>β</i>′ and <i>γ</i>″ nano-precipitation with high fractions are the main strengthening phases, leading to a strengthening increment of ~277 MPa. Moreover, the multi-element alloying in this study promotes the basal-prismatic network strengthening structure, composed of <i>β</i>′ nano-precipitation with (1-210) habit planes, <i>γ</i>″ nano-precipitation with (0001) habit planes, basal plane stacking faults and 14H-long period stacking ordered phase. In addition, the dislocations and fine grains introduced by the hot-extrusion process not only accelerate the precipitation rate of nanostructure and thus improve the ageing hardening efficiency, but also facilitate the formation of more uniform and finer nano-precipitation. Thus, it is proposed that introducing nano-precipitates network into fine-grained structure is an effective strategy for developing high-strength Mg alloys.
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spelling doaj.art-94ac29dc68bc461cb7654ad98d56e3a42023-11-17T17:17:24ZengMDPI AGNanomaterials2079-49912023-03-01137121910.3390/nano13071219Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-PrecipitationJinshu Xie0Jinghuai Zhang1Shujuan Liu2Zihao You3Zhi Zhang4Tengfei Zhao5Xiaobo Zhang6Ruizhi Wu7Key Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaDepartment of Materials Physics and Chemistry, Harbin Institute of Technology, Harbin 150001, ChinaKey Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaKey Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaJiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing Institute of Technology, Nanjing 211167, ChinaKey Laboratory of Superlight Material and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, ChinaA high-performance Mg-10Gd-4Dy-1.5Ag-1Zn-0.5Zr (wt.%, EQ142X) alloy was designed by multi-element composite addition in this work, obtaining a high yield strength (~396 MPa) and ultimate tensile strength (~451 MPa) after hot extrusion and ageing. The high strength is mainly related to fine grains and nano-precipitates, especially the latter. <i>β</i>′ and <i>γ</i>″ nano-precipitation with high fractions are the main strengthening phases, leading to a strengthening increment of ~277 MPa. Moreover, the multi-element alloying in this study promotes the basal-prismatic network strengthening structure, composed of <i>β</i>′ nano-precipitation with (1-210) habit planes, <i>γ</i>″ nano-precipitation with (0001) habit planes, basal plane stacking faults and 14H-long period stacking ordered phase. In addition, the dislocations and fine grains introduced by the hot-extrusion process not only accelerate the precipitation rate of nanostructure and thus improve the ageing hardening efficiency, but also facilitate the formation of more uniform and finer nano-precipitation. Thus, it is proposed that introducing nano-precipitates network into fine-grained structure is an effective strategy for developing high-strength Mg alloys.https://www.mdpi.com/2079-4991/13/7/1219magnesium alloysageingnano-precipitationmechanical properties
spellingShingle Jinshu Xie
Jinghuai Zhang
Shujuan Liu
Zihao You
Zhi Zhang
Tengfei Zhao
Xiaobo Zhang
Ruizhi Wu
Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
Nanomaterials
magnesium alloys
ageing
nano-precipitation
mechanical properties
title Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
title_full Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
title_fullStr Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
title_full_unstemmed Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
title_short Developing Mg-Gd-Dy-Ag-Zn-Zr Alloy with High Strength via Nano-Precipitation
title_sort developing mg gd dy ag zn zr alloy with high strength via nano precipitation
topic magnesium alloys
ageing
nano-precipitation
mechanical properties
url https://www.mdpi.com/2079-4991/13/7/1219
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