Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression

The combined effect of dissolved ions and water temperature on the adsorption of a xanthate collector on chalcopyrite and pentlandite was investigated using multiple linear regression. Cationic species improved the adsorption of the collector on sulphide minerals through xanthate adsorption activati...

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Main Authors: Ngoni Mhonde, Nora Schreithofer, Kirsten Corin, Mikko Mäkelä
Format: Article
Language:English
Published: MDPI AG 2020-08-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/10/9/733
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author Ngoni Mhonde
Nora Schreithofer
Kirsten Corin
Mikko Mäkelä
author_facet Ngoni Mhonde
Nora Schreithofer
Kirsten Corin
Mikko Mäkelä
author_sort Ngoni Mhonde
collection DOAJ
description The combined effect of dissolved ions and water temperature on the adsorption of a xanthate collector on chalcopyrite and pentlandite was investigated using multiple linear regression. Cationic species improved the adsorption of the collector on sulphide minerals through xanthate adsorption activation. Thiosulphate ions generally had a negative effect on collector adsorption, and the interaction of thiosulphate ions and cations effectively reduced collector adsorption on the sulphide minerals. With regards to temperature variation caused by seasonal variation, this study suggests that temperature can influence the adsorption of collectors in the flotation process and this should be approached on a case by case basis as it seems to differ with the type of mineral under investigation. These fundamental results prompt a discussion on how complex water matrices can affect interactions of reagents and sulphide minerals at the solid–liquid interface and the possible effect on flotation performance.
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spelling doaj.art-9503c99672694e8ba58f44f398dcad6f2023-11-20T10:41:42ZengMDPI AGMinerals2075-163X2020-08-0110973310.3390/min10090733Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear RegressionNgoni Mhonde0Nora Schreithofer1Kirsten Corin2Mikko Mäkelä3Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, FIN-00076 Aalto, FinlandDepartment of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, FIN-00076 Aalto, FinlandCentre for Minerals Research, Chemical Engineering Department, University of Cape Town, Rondebosch, Cape Town 7701, South AfricaVTT Technical Research Centre of Finland Ltd., FI-02044 Espoo, FinlandThe combined effect of dissolved ions and water temperature on the adsorption of a xanthate collector on chalcopyrite and pentlandite was investigated using multiple linear regression. Cationic species improved the adsorption of the collector on sulphide minerals through xanthate adsorption activation. Thiosulphate ions generally had a negative effect on collector adsorption, and the interaction of thiosulphate ions and cations effectively reduced collector adsorption on the sulphide minerals. With regards to temperature variation caused by seasonal variation, this study suggests that temperature can influence the adsorption of collectors in the flotation process and this should be approached on a case by case basis as it seems to differ with the type of mineral under investigation. These fundamental results prompt a discussion on how complex water matrices can affect interactions of reagents and sulphide minerals at the solid–liquid interface and the possible effect on flotation performance.https://www.mdpi.com/2075-163X/10/9/733pentlanditechalcopyriteadsorptionmultiple linear regressiontemperaturepassivation
spellingShingle Ngoni Mhonde
Nora Schreithofer
Kirsten Corin
Mikko Mäkelä
Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
Minerals
pentlandite
chalcopyrite
adsorption
multiple linear regression
temperature
passivation
title Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
title_full Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
title_fullStr Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
title_full_unstemmed Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
title_short Assessing the Combined Effect of Water Temperature and Complex Water Matrices on Xanthate Adsorption Using Multiple Linear Regression
title_sort assessing the combined effect of water temperature and complex water matrices on xanthate adsorption using multiple linear regression
topic pentlandite
chalcopyrite
adsorption
multiple linear regression
temperature
passivation
url https://www.mdpi.com/2075-163X/10/9/733
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AT noraschreithofer assessingthecombinedeffectofwatertemperatureandcomplexwatermatricesonxanthateadsorptionusingmultiplelinearregression
AT kirstencorin assessingthecombinedeffectofwatertemperatureandcomplexwatermatricesonxanthateadsorptionusingmultiplelinearregression
AT mikkomakela assessingthecombinedeffectofwatertemperatureandcomplexwatermatricesonxanthateadsorptionusingmultiplelinearregression