Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate)
In the title complex, [Zn(C14H9N5)2](ClO4)2, 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the ZnII ion assumes a distorted octahedral ZnN6 coordination geometry. There is a weak π–π stacking interaction between symmetry-re...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009-11-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680903877X |
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author | Long Miao Xie Lin Meng Jing Min Shi |
author_facet | Long Miao Xie Lin Meng Jing Min Shi |
author_sort | Long Miao Xie |
collection | DOAJ |
description | In the title complex, [Zn(C14H9N5)2](ClO4)2, 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the ZnII ion assumes a distorted octahedral ZnN6 coordination geometry. There is a weak π–π stacking interaction between symmetry-related triazolyl rings with a centroid–centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between the rings. |
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id | doaj.art-9506e085efb94c3e9cca1fd40a5bc274 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-24T00:40:46Z |
publishDate | 2009-11-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-9506e085efb94c3e9cca1fd40a5bc2742022-12-21T17:23:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1279m127910.1107/S160053680903877XBis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate)Long Miao XieLin MengJing Min ShiIn the title complex, [Zn(C14H9N5)2](ClO4)2, 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the ZnII ion assumes a distorted octahedral ZnN6 coordination geometry. There is a weak π–π stacking interaction between symmetry-related triazolyl rings with a centroid–centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between the rings.http://scripts.iucr.org/cgi-bin/paper?S160053680903877X |
spellingShingle | Long Miao Xie Lin Meng Jing Min Shi Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) Acta Crystallographica Section E |
title | Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) |
title_full | Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) |
title_fullStr | Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) |
title_full_unstemmed | Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) |
title_short | Bis[2-(1H-1,2,4-triazol-1-yl-κN2)-1,10-phenanthroline-κ2N,N′]zinc(II) bis(perchlorate) |
title_sort | bis 2 1h 1 2 4 triazol 1 yl amp 954 n2 1 10 phenanthroline amp 954 2n n amp 8242 zinc ii bis perchlorate |
url | http://scripts.iucr.org/cgi-bin/paper?S160053680903877X |
work_keys_str_mv | AT longmiaoxie bis21h124triazol1ylamp954n2110phenanthrolineamp9542nnamp8242zinciibisperchlorate AT linmeng bis21h124triazol1ylamp954n2110phenanthrolineamp9542nnamp8242zinciibisperchlorate AT jingminshi bis21h124triazol1ylamp954n2110phenanthrolineamp9542nnamp8242zinciibisperchlorate |