Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries

The cyclic stability of the MnOx cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn3+ disproportionation produces Mn2+ caused by Jahn Teller lattice distortion effect in the process of Zn2+ inter/deintercalation. This mini review summarized bulk-phase and interface sta...

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Main Authors: Gaoqi Yang, Houzhao Wan
Format: Article
Language:English
Published: Frontiers Media S.A. 2022-09-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2022.1000337/full
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author Gaoqi Yang
Gaoqi Yang
Houzhao Wan
Houzhao Wan
author_facet Gaoqi Yang
Gaoqi Yang
Houzhao Wan
Houzhao Wan
author_sort Gaoqi Yang
collection DOAJ
description The cyclic stability of the MnOx cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn3+ disproportionation produces Mn2+ caused by Jahn Teller lattice distortion effect in the process of Zn2+ inter/deintercalation. This mini review summarized bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries from the regulation of bulk electronic state of manganese oxide improves its structural stability and the formation of beneficial SEI layer at the interface of electrolyte. It provides theoretical support for the design of manganese oxide cathode materials for aqueous zinc ion batteries with high stability.
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spelling doaj.art-9524e740694440f992325861df5f21e62022-12-22T04:27:05ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-09-011010.3389/fchem.2022.10003371000337Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteriesGaoqi Yang0Gaoqi Yang1Houzhao Wan2Houzhao Wan3Hubei Yangtze Memory Laboratories, Wuhan, ChinaSchool of Microelectronics and Faculty of Physics and Electronics Science, Hubei University, Wuhan, ChinaHubei Yangtze Memory Laboratories, Wuhan, ChinaSchool of Microelectronics and Faculty of Physics and Electronics Science, Hubei University, Wuhan, ChinaThe cyclic stability of the MnOx cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn3+ disproportionation produces Mn2+ caused by Jahn Teller lattice distortion effect in the process of Zn2+ inter/deintercalation. This mini review summarized bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries from the regulation of bulk electronic state of manganese oxide improves its structural stability and the formation of beneficial SEI layer at the interface of electrolyte. It provides theoretical support for the design of manganese oxide cathode materials for aqueous zinc ion batteries with high stability.https://www.frontiersin.org/articles/10.3389/fchem.2022.1000337/fullMnOxstabilitycathodeinterfacezinc ion battery
spellingShingle Gaoqi Yang
Gaoqi Yang
Houzhao Wan
Houzhao Wan
Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
Frontiers in Chemistry
MnOx
stability
cathode
interface
zinc ion battery
title Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
title_full Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
title_fullStr Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
title_full_unstemmed Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
title_short Bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries
title_sort bulk phase and interface stability strategies of manganese oxide cathodes for aqueous zn mnox batteries
topic MnOx
stability
cathode
interface
zinc ion battery
url https://www.frontiersin.org/articles/10.3389/fchem.2022.1000337/full
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