The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas

The applications of different mixed metal oxides were explored for the capture of CO2 and convert of CO2 to syn-gas. The several samples of the mixed metal oxides were prepared by the sol-gel, solid-solid fusion, precipitation, molten salt and template methods in order to investigate the performance...

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Main Authors: Sajan Babhare, Reshma Raskar, Komal Bobade, Abaji Gaikwad
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2015-08-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/19361
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author Sajan Babhare
Reshma Raskar
Komal Bobade
Abaji Gaikwad
author_facet Sajan Babhare
Reshma Raskar
Komal Bobade
Abaji Gaikwad
author_sort Sajan Babhare
collection DOAJ
description The applications of different mixed metal oxides were explored for the capture of CO2 and convert of CO2 to syn-gas. The several samples of the mixed metal oxides were prepared by the sol-gel, solid-solid fusion, precipitation, molten salt and template methods in order to investigate the performance of mixed mtal oxides to the CO2 applications. These samples were calcined for the 3 h in air at 900 oC. The mixed metal oxides samples were characterized by acidity/basicity, surface area, XRD pattern, SEM images and to capture CO2. The basicity and surface area of the samples of mixed metal oxides were found to be in the range from 0.7 to 15.7 mmol.g-1 and 2.24 to 138.76 m2.g-1, respectively. The ob-tained results of prepared mixed metal oxides by different method were compared for the purpose of searching the efficient materials. The temperature profiles of the captured CO2 by the samples of mixed metal oxides were obtained in the range 100 to 800 oC. The captured CO2 was found to be in the range from 7.36 to 26.93 wt.%. The conversions of CO2 by methane were explored to syn-gas over the mixed metal oxides including the calcium iron lanthanum mixed metal oxides and (5 wt.%) Pd/Al2O3 at 700 oC with the gas hourly space velocities (GHSV) 6000 ml.h-1.g-1 of methane, 6000 ml.h-1.g-1 of CO2 and 24000 ml.h-1.g-1 of helium. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)
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spelling doaj.art-95344c06435e43b3a3969e62621ccfd62023-09-22T03:52:57ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932015-08-0110212514210.9767/bcrec.10.2.7381.125-1428082The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-GasSajan Babhare0Reshma Raskar1Komal Bobade2Abaji Gaikwad3Chemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411008, IndiaChemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411008, IndiaChemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411008, IndiaChemical Engineering and Process Development Division, National Chemical Laboratory, Pune 411008, IndiaThe applications of different mixed metal oxides were explored for the capture of CO2 and convert of CO2 to syn-gas. The several samples of the mixed metal oxides were prepared by the sol-gel, solid-solid fusion, precipitation, molten salt and template methods in order to investigate the performance of mixed mtal oxides to the CO2 applications. These samples were calcined for the 3 h in air at 900 oC. The mixed metal oxides samples were characterized by acidity/basicity, surface area, XRD pattern, SEM images and to capture CO2. The basicity and surface area of the samples of mixed metal oxides were found to be in the range from 0.7 to 15.7 mmol.g-1 and 2.24 to 138.76 m2.g-1, respectively. The ob-tained results of prepared mixed metal oxides by different method were compared for the purpose of searching the efficient materials. The temperature profiles of the captured CO2 by the samples of mixed metal oxides were obtained in the range 100 to 800 oC. The captured CO2 was found to be in the range from 7.36 to 26.93 wt.%. The conversions of CO2 by methane were explored to syn-gas over the mixed metal oxides including the calcium iron lanthanum mixed metal oxides and (5 wt.%) Pd/Al2O3 at 700 oC with the gas hourly space velocities (GHSV) 6000 ml.h-1.g-1 of methane, 6000 ml.h-1.g-1 of CO2 and 24000 ml.h-1.g-1 of helium. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)https://journal.bcrec.id/index.php/bcrec/article/view/19361sol-gel methodcapture of co2mixed metal oxidessolid-solid fusion methodsyn-gas
spellingShingle Sajan Babhare
Reshma Raskar
Komal Bobade
Abaji Gaikwad
The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
Bulletin of Chemical Reaction Engineering & Catalysis
sol-gel method
capture of co2
mixed metal oxides
solid-solid fusion method
syn-gas
title The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
title_full The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
title_fullStr The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
title_full_unstemmed The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
title_short The Applications of Mixed Metal Oxides to Capture the CO2 and Convert to Syn-Gas
title_sort applications of mixed metal oxides to capture the co2 and convert to syn gas
topic sol-gel method
capture of co2
mixed metal oxides
solid-solid fusion method
syn-gas
url https://journal.bcrec.id/index.php/bcrec/article/view/19361
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