Ru complexes of Hoveyda–Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions

Ru complexes of Hoveyda–Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions

Hoveyda–Grubbs type catalysts with cationic tags on NHC ligands were linker-free immobilized on the surface of lamellar zeolitic supports (MCM-22, MCM-56, MCM-36) and on mesoporous molecular sieves SBA-15. The activity of prepared hybrid catalysts was tested in olefin metathesis reactions: the activ...

Full description

Bibliographic Details
Main Authors:	Hynek Balcar, Naděžda Žilková, Martin Kubů, Michal Mazur, Zdeněk Bastl, Jiří Čejka
Format:	Article
Language:	English
Published:	Beilstein-Institut 2015-11-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	Hoveyda–Grubbs type catalyst hybrid catalysts lamellar zeolites non-covalent immobilization olefin metathesis
Online Access:	https://doi.org/10.3762/bjoc.11.225

Similar Items

Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido(2-{[(2-methoxyethyl)(methyl)amino]methyl}benzylidene)ruthenium
by: Gunay Z. Mammadova, et al.
Published: (2024-01-01)

Hoveyda–Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves MCM-41 and SBA-15
by: Hynek Balcar, et al.
Published: (2011-01-01)

Functionalization of Ruthenium Olefin-Metathesis Catalysts for Interdisciplinary Studies in Chemistry and Biology
by: Takashi Matsuo
Published: (2021-03-01)

Crystal structure of [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]dichlorido{2-[1-(dimethylamino)ethyl]benzylidene}ruthenium including an unknown solvate
by: Kirill B. Polyanskii, et al.
Published: (2019-03-01)

New library of aminosulfonyl-tagged Hoveyda–Grubbs type complexes: Synthesis, kinetic studies and activity in olefin metathesis transformations
by: Etienne Borré, et al.
Published: (2010-12-01)

Heterogeneous catalysts for olefin metathesis
by: Natalia Barteczko, et al.
Published: (2023-04-01)

Metátese de olefinas no Brasil: "Brazil is romping it!" Olefin metathesis in Brazil: Brazil is romping it!
by: José Milton E. Matos, et al.
Published: (2007-04-01)

Tandem catalysis of ring-closing metathesis/atom transfer radical reactions with homobimetallic ruthenium–arene complexes
by: Yannick Borguet, et al.
Published: (2010-12-01)

Reactivity of Tungsten-aryloxides with Hydrosilane Cocatalysts in Olefin Metathesis
by: Baibich Ione M., et al.
Published: (2002-01-01)

Cardanol-Based Materials as Natural Precursors for Olefin Metathesis
by: Giuseppe Vasapollo, et al.
Published: (2011-08-01)

Practical Preparation of (4R,5R,E)-methyl 5-(tert-butyldimethylsilyloxy)-4-hydroxyhepta-2,6-dienoate
by: Yudhi Dwi Kurniawan, et al.
Published: (2013-10-01)

Design of Heterogeneous Hoveyda–Grubbs Second-Generation Catalyst–Lipase Conjugates
by: Anthony Neville, et al.
Published: (2016-12-01)

On the stereoselectivity of the cross metathesis of olefins catalyzed by a second-generation catalyst
by: J. Pablo Martínez, et al.
Published: (2022-12-01)

The intriguing modeling of cis–trans selectivity in ruthenium-catalyzed olefin metathesis
by: Naeimeh Bahri-Laleh, et al.
Published: (2011-01-01)

Stereochemistry of ring-opening/cross metathesis reactions of exo- and endo-7-oxabicyclo[2.2.1]hept-5-ene-2-carbonitriles with allyl alcohol and allyl acetate
by: Piotr Wałejko, et al.
Published: (2015-10-01)

Application of New Efficient Hoveyda–Grubbs Catalysts Comprising an N→Ru Coordinate Bond in a Six-Membered Ring for the Synthesis of Natural Product-Like Cyclopenta[<i>b</i>]furo[2,3-<i>c</i>]pyrroles
by: Alexandra S. Antonova, et al.
Published: (2020-11-01)

The Influence of Various <i>N</i>-Heterocyclic Carbene Ligands on Activity of Nitro-Activated Olefin Metathesis Catalysts
by: Michał Pieczykolan, et al.
Published: (2020-05-01)

Iron-Catalyzed Carbonyl–Alkyne and Carbonyl–Olefin Metathesis Reactions
by: Benedikt W. Grau, et al.
Published: (2020-09-01)

Ruthenium Metathesis Catalysts with Imidazole Ligands
by: Peng Ma, et al.
Published: (2023-01-01)

Fast Initiating Furan-Containing Hoveyda-Type Complexes: Synthesis and Applications in Metathesis Reactions
by: Maryana Nadirova, et al.
Published: (2022-08-01)

Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene
by: Suresh Mandava, et al.
Published: (2020-06-01)

Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands
by: Veronica Paradiso, et al.
Published: (2018-12-01)

Improved Metathesis Lifetime: Chelating Pyridinyl-Alcoholato Ligands in the Second Generation Grubbs Precatalyst
by: Jean I. du Toit, et al.
Published: (2014-04-01)

Decomposition of Ruthenium Olefin Metathesis Catalyst
by: Magdalena Jawiczuk, et al.
Published: (2020-08-01)

<sup>1</sup>H NMR Analysis of the Metathesis Reaction between 1-Hexene and (<i>E</i>)-Anethole Using Grubbs 2nd Generation Catalyst: Effect of Reaction Conditions on (<i>E</i>)-1-(4-Methoxyphenyl)-1-hexene Formation and Decomposition
by: Marthinus Rudi Swart, et al.
Published: (2021-12-01)

Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst
by: Michel Wong Chi Man, et al.
Published: (2010-08-01)

New metathesis catalyst bearing chromanyl moieties at the N-heterocyclic carbene ligand
by: Agnieszka Hryniewicka, et al.
Published: (2015-12-01)

Cross-metathesis of polynorbornene with polyoctenamer: a kinetic study
by: Yulia I. Denisova, et al.
Published: (2015-10-01)

Olefin metathesis in multiblock copolymer synthesis
by: Maria L. Gringolts, et al.
Published: (2019-01-01)

Aqueous olefin metathesis: recent developments and applications
by: Valerio Sabatino, et al.
Published: (2019-02-01)

Olefin metathesis in air
by: Lorenzo Piola, et al.
Published: (2015-10-01)

The activity of indenylidene derivatives in olefin metathesis catalysts
by: Maria Voccia, et al.
Published: (2018-11-01)

MOF Encapsulation of Ru Olefin Metathesis Catalysts to Block Catalyst Decomposition
by: Gerard Pareras, et al.
Published: (2020-06-01)

Metathesis access to monocyclic iminocyclitol-based therapeutic agents
by: Ileana Dragutan, et al.
Published: (2011-05-01)

Synthesis of Electronically Modified Ru-Based Neutral 16 VE Allenylidene Olefin Metathesis Precatalysts
by: Siegfried Blechert, et al.
Published: (2012-05-01)

Application of olefin metathesis in the synthesis of functionalized polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials
by: Patrycja Żak, et al.
Published: (2019-02-01)

A reação de metátese de olefinas: reorganização e ciclização de compostos orgânicos The olefin metathesis reaction: reorganization and ciclization of organic compounds
by: Daniel Frederico, et al.
Published: (2005-08-01)

Preparation of Ruthenium Olefin Metathesis Catalysts Immobilized on MOF, SBA-15, and 13X for Probing Heterogeneous Boomerang Effect
by: Artur Chołuj, et al.
Published: (2020-04-01)

Catalysis of linear alkene metathesis by Grubbs-type ruthenium alkylidene complexes containing hemilabile α,α-diphenyl-(monosubstituted-pyridin-2-yl)methanolato ligands
by: Tegene T. Tole, et al.
Published: (2019-01-01)

A tutorial review of stereoretentive olefin metathesis based on ruthenium dithiolate catalysts
by: Daniel S. Müller, et al.
Published: (2018-12-01)