Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes

Treating wastewater from textile plants using membrane distillation (MD) has great potential due to the high-salinity wastes and availability of waste heat. However, textile wastewaters also contain surfactants, which compromise the essential hydrophobic feature of the membrane, causing membrane wet...

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Main Authors: Jesús Villalobos García, Noel Dow, Nicholas Milne, Jianhua Zhang, Leslie Naidoo, Stephen Gray, Mikel Duke
Format: Article
Language:English
Published: MDPI AG 2018-06-01
Series:Membranes
Subjects:
Online Access:http://www.mdpi.com/2077-0375/8/2/31
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author Jesús Villalobos García
Noel Dow
Nicholas Milne
Jianhua Zhang
Leslie Naidoo
Stephen Gray
Mikel Duke
author_facet Jesús Villalobos García
Noel Dow
Nicholas Milne
Jianhua Zhang
Leslie Naidoo
Stephen Gray
Mikel Duke
author_sort Jesús Villalobos García
collection DOAJ
description Treating wastewater from textile plants using membrane distillation (MD) has great potential due to the high-salinity wastes and availability of waste heat. However, textile wastewaters also contain surfactants, which compromise the essential hydrophobic feature of the membrane, causing membrane wetting. To address this wetting issue, a custom-made membrane consisting of a hydrophilic layer coated on hydrophobic polytetrafluoroethylene (PTFE) was tested on textile wastewater in a pilot MD setup, and compared with a conventional hydrophobic PTFE membrane. The test was carried out with a feed temperature of 60 °C, and a permeate temperature of 45 °C. The overall salt rejection of both membranes was very high, at 99%. However, the hydrophobic membrane showed rising permeate electrical conductivity, which was attributed to wetting of the membrane. Meanwhile, the hydrophilic-coated membrane showed continually declining electrical conductivity demonstrating an intact membrane that resisted wetting from the surfactants. Despite this positive result, the coated membrane did not survive a simple sodium hydroxide clean, which would be typically applied to a membrane process. This brief study showed the viability of membrane distillation membranes on real textile wastewaters containing surfactants using hydrophilic-coated hydrophobic PTFE, but the cleaning process required for membranes needs optimization.
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spelling doaj.art-95444d0c29f842ed966d494dd83eb09d2023-08-02T01:10:51ZengMDPI AGMembranes2077-03752018-06-01823110.3390/membranes8020031membranes8020031Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) MembranesJesús Villalobos García0Noel Dow1Nicholas Milne2Jianhua Zhang3Leslie Naidoo4Stephen Gray5Mikel Duke6Institute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaInstitute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaInstitute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaInstitute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaAustralian Textile Mills Pty Ltd., Wangaratta, VIC 3677, AustraliaInstitute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaInstitute for Sustainable Industries & Liveable Cities, Victoria University, P.O. Box 14428, Melbourne, VIC 8001, AustraliaTreating wastewater from textile plants using membrane distillation (MD) has great potential due to the high-salinity wastes and availability of waste heat. However, textile wastewaters also contain surfactants, which compromise the essential hydrophobic feature of the membrane, causing membrane wetting. To address this wetting issue, a custom-made membrane consisting of a hydrophilic layer coated on hydrophobic polytetrafluoroethylene (PTFE) was tested on textile wastewater in a pilot MD setup, and compared with a conventional hydrophobic PTFE membrane. The test was carried out with a feed temperature of 60 °C, and a permeate temperature of 45 °C. The overall salt rejection of both membranes was very high, at 99%. However, the hydrophobic membrane showed rising permeate electrical conductivity, which was attributed to wetting of the membrane. Meanwhile, the hydrophilic-coated membrane showed continually declining electrical conductivity demonstrating an intact membrane that resisted wetting from the surfactants. Despite this positive result, the coated membrane did not survive a simple sodium hydroxide clean, which would be typically applied to a membrane process. This brief study showed the viability of membrane distillation membranes on real textile wastewaters containing surfactants using hydrophilic-coated hydrophobic PTFE, but the cleaning process required for membranes needs optimization.http://www.mdpi.com/2077-0375/8/2/31membrane distillationhydrophilic membranepolytetrafluoroethylenedesalination
spellingShingle Jesús Villalobos García
Noel Dow
Nicholas Milne
Jianhua Zhang
Leslie Naidoo
Stephen Gray
Mikel Duke
Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
Membranes
membrane distillation
hydrophilic membrane
polytetrafluoroethylene
desalination
title Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
title_full Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
title_fullStr Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
title_full_unstemmed Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
title_short Membrane Distillation Trial on Textile Wastewater Containing Surfactants Using Hydrophobic and Hydrophilic-Coated Polytetrafluoroethylene (PTFE) Membranes
title_sort membrane distillation trial on textile wastewater containing surfactants using hydrophobic and hydrophilic coated polytetrafluoroethylene ptfe membranes
topic membrane distillation
hydrophilic membrane
polytetrafluoroethylene
desalination
url http://www.mdpi.com/2077-0375/8/2/31
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