Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles

The use of polymeric nanocomposites has arisen as a promising solution to take advantage of the properties of nanoparticles (NPs) in diverse applications (e.g., water treatment, catalysis), while overcoming the drawbacks of free-standing nanoparticles (e.g., aggregation or accidental release). In mo...

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Main Authors: Suset Barroso-Solares, Paula Cimavilla-Roman, Miguel Angel Rodriguez-Perez, Javier Pinto
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/5/996
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author Suset Barroso-Solares
Paula Cimavilla-Roman
Miguel Angel Rodriguez-Perez
Javier Pinto
author_facet Suset Barroso-Solares
Paula Cimavilla-Roman
Miguel Angel Rodriguez-Perez
Javier Pinto
author_sort Suset Barroso-Solares
collection DOAJ
description The use of polymeric nanocomposites has arisen as a promising solution to take advantage of the properties of nanoparticles (NPs) in diverse applications (e.g., water treatment, catalysis), while overcoming the drawbacks of free-standing nanoparticles (e.g., aggregation or accidental release). In most of the cases, the amount and size of the NPs will affect the stability of the composite as well as their performance. Therefore, a detailed characterization of the NPs present on the nanocomposites, including their quantification, is of vital importance for the optimization of these systems. However, the determination of the NPs load is often carried out by destructive techniques such as TGA or ICP-OES, the development of non-invasive approaches to that aim being necessary. In this work, the amount of silver NPs synthesized directly on the surface of melamine (ME) foams is studied using two non-invasive approaches: colorimetry and X-ray radiography. The obtained results show that the amount of silver NPs can be successfully determined from the luminosity and global color changes of the surface of the foams, as well as from the X-ray attenuance.
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spelling doaj.art-956048a2ead84df1a85017d9753cf77e2023-11-19T22:42:25ZengMDPI AGPolymers2073-43602020-04-0112599610.3390/polym12050996Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver NanoparticlesSuset Barroso-Solares0Paula Cimavilla-Roman1Miguel Angel Rodriguez-Perez2Javier Pinto3Cellular Materials Laboratory (CellMat), Condensed Matter Physics Department, University of Valladolid, 47011 Valladolid, SpainCellular Materials Laboratory (CellMat), Condensed Matter Physics Department, University of Valladolid, 47011 Valladolid, SpainCellular Materials Laboratory (CellMat), Condensed Matter Physics Department, University of Valladolid, 47011 Valladolid, SpainCellular Materials Laboratory (CellMat), Condensed Matter Physics Department, University of Valladolid, 47011 Valladolid, SpainThe use of polymeric nanocomposites has arisen as a promising solution to take advantage of the properties of nanoparticles (NPs) in diverse applications (e.g., water treatment, catalysis), while overcoming the drawbacks of free-standing nanoparticles (e.g., aggregation or accidental release). In most of the cases, the amount and size of the NPs will affect the stability of the composite as well as their performance. Therefore, a detailed characterization of the NPs present on the nanocomposites, including their quantification, is of vital importance for the optimization of these systems. However, the determination of the NPs load is often carried out by destructive techniques such as TGA or ICP-OES, the development of non-invasive approaches to that aim being necessary. In this work, the amount of silver NPs synthesized directly on the surface of melamine (ME) foams is studied using two non-invasive approaches: colorimetry and X-ray radiography. The obtained results show that the amount of silver NPs can be successfully determined from the luminosity and global color changes of the surface of the foams, as well as from the X-ray attenuance.https://www.mdpi.com/2073-4360/12/5/996noble metal nanoparticlespolymer foamnanocompositescolorimetryX-ray radiography
spellingShingle Suset Barroso-Solares
Paula Cimavilla-Roman
Miguel Angel Rodriguez-Perez
Javier Pinto
Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
Polymers
noble metal nanoparticles
polymer foam
nanocomposites
colorimetry
X-ray radiography
title Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
title_full Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
title_fullStr Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
title_full_unstemmed Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
title_short Non-Invasive Approaches for the Evaluation of the Functionalization of Melamine Foams with In-Situ Synthesized Silver Nanoparticles
title_sort non invasive approaches for the evaluation of the functionalization of melamine foams with in situ synthesized silver nanoparticles
topic noble metal nanoparticles
polymer foam
nanocomposites
colorimetry
X-ray radiography
url https://www.mdpi.com/2073-4360/12/5/996
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AT paulacimavillaroman noninvasiveapproachesfortheevaluationofthefunctionalizationofmelaminefoamswithinsitusynthesizedsilvernanoparticles
AT miguelangelrodriguezperez noninvasiveapproachesfortheevaluationofthefunctionalizationofmelaminefoamswithinsitusynthesizedsilvernanoparticles
AT javierpinto noninvasiveapproachesfortheevaluationofthefunctionalizationofmelaminefoamswithinsitusynthesizedsilvernanoparticles