CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification
Premix membrane emulsification is a quick and efficient method to prepare emulsion. Pre-emulsion was prepared by dissolving 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and cellulose acetate butyrate (CAB) in ethyl acetate, and the mixture was added to an aqueous solution conta...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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AIP Publishing LLC
2020-12-01
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| Series: | AIP Advances |
| Online Access: | http://dx.doi.org/10.1063/5.0031358 |
| _version_ | 1828947752906653696 |
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| author | Jiechao Wang Chongwei An Baoyun Ye Ruixuan Xu Qian Liu Jingyu Wang Jun Dong |
| author_facet | Jiechao Wang Chongwei An Baoyun Ye Ruixuan Xu Qian Liu Jingyu Wang Jun Dong |
| author_sort | Jiechao Wang |
| collection | DOAJ |
| description | Premix membrane emulsification is a quick and efficient method to prepare emulsion. Pre-emulsion was prepared by dissolving 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and cellulose acetate butyrate (CAB) in ethyl acetate, and the mixture was added to an aqueous solution containing a surfactant. Then, the droplet uniform emulsion through the transmembrane was formed. The composites with the core–shell structure were obtained after evaporating the solvent. The results displayed that the morphological structure of CL-20 based composite could change from the dumbbell-shaped structure to spherical structure with an increase in the CAB content. Based on the impact sensitivity and thermal properties, the composite enhanced the safety. Meanwhile, a remarkable enhancement in the decomposition peak temperature (Tp0) and the critical temperature of the explosion (Tb) at a relatively low content of CAB (3 wt. %, 5 wt. % and 10 wt. %) was also noted. This approach provides a faster way for the design and preparation of polymer composites. |
| first_indexed | 2024-12-14T05:34:22Z |
| format | Article |
| id | doaj.art-95605ddf2850486a84c8befedd1ad447 |
| institution | Directory Open Access Journal |
| issn | 2158-3226 |
| language | English |
| last_indexed | 2024-12-14T05:34:22Z |
| publishDate | 2020-12-01 |
| publisher | AIP Publishing LLC |
| record_format | Article |
| series | AIP Advances |
| spelling | doaj.art-95605ddf2850486a84c8befedd1ad4472022-12-21T23:15:14ZengAIP Publishing LLCAIP Advances2158-32262020-12-011012125005125005-910.1063/5.0031358CL-20/CAB energetic composite microspheres prepared by premix membrane emulsificationJiechao Wang0Chongwei An1Baoyun Ye2Ruixuan Xu3Qian Liu4Jingyu Wang5Jun Dong6School of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaSchool of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaSchool of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaSchool of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaSchool of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaSchool of Environment and Safety Engineering, North University of China, Taiyuan 030051, Shanxi, ChinaLuzhou North Chemical Industries Co., Ltd., Luzhou 646000, Sichuan, ChinaPremix membrane emulsification is a quick and efficient method to prepare emulsion. Pre-emulsion was prepared by dissolving 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and cellulose acetate butyrate (CAB) in ethyl acetate, and the mixture was added to an aqueous solution containing a surfactant. Then, the droplet uniform emulsion through the transmembrane was formed. The composites with the core–shell structure were obtained after evaporating the solvent. The results displayed that the morphological structure of CL-20 based composite could change from the dumbbell-shaped structure to spherical structure with an increase in the CAB content. Based on the impact sensitivity and thermal properties, the composite enhanced the safety. Meanwhile, a remarkable enhancement in the decomposition peak temperature (Tp0) and the critical temperature of the explosion (Tb) at a relatively low content of CAB (3 wt. %, 5 wt. % and 10 wt. %) was also noted. This approach provides a faster way for the design and preparation of polymer composites.http://dx.doi.org/10.1063/5.0031358 |
| spellingShingle | Jiechao Wang Chongwei An Baoyun Ye Ruixuan Xu Qian Liu Jingyu Wang Jun Dong CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification AIP Advances |
| title | CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification |
| title_full | CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification |
| title_fullStr | CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification |
| title_full_unstemmed | CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification |
| title_short | CL-20/CAB energetic composite microspheres prepared by premix membrane emulsification |
| title_sort | cl 20 cab energetic composite microspheres prepared by premix membrane emulsification |
| url | http://dx.doi.org/10.1063/5.0031358 |
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