Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color

Silver deposition-based electrochromic (EC) device enabled various optical states by using either the electrodeposition of silver thin films or silver nanoparticles on an indium tin oxide electrode. These optical states, including chromatic colors such as cyan, magenta, yellow, and green, are based...

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Main Authors: Shunsuke KIMURA, Hikaru WAKATSUKI, Kazuki NAKAMURA, Norihisa KOBAYASHI
Format: Article
Language:English
Published: The Electrochemical Society of Japan 2022-04-01
Series:Electrochemistry
Subjects:
Online Access:https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00006/_html/-char/en
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author Shunsuke KIMURA
Hikaru WAKATSUKI
Kazuki NAKAMURA
Norihisa KOBAYASHI
author_facet Shunsuke KIMURA
Hikaru WAKATSUKI
Kazuki NAKAMURA
Norihisa KOBAYASHI
author_sort Shunsuke KIMURA
collection DOAJ
description Silver deposition-based electrochromic (EC) device enabled various optical states by using either the electrodeposition of silver thin films or silver nanoparticles on an indium tin oxide electrode. These optical states, including chromatic colors such as cyan, magenta, yellow, and green, are based on absorption by the localized surface plasmon resonance of silver nanoparticles. However, an ideal counter-reaction material that does not affect the color representation by silver nanoparticles and does not dissolve the deposited silver has not been reported. To achieve both color retention and chromatic color representation, MnO2 was utilized as the counter electrode material. The EC properties of the novel device with the MnO2 counter electrode were investigated in terms of charge density and its ability to change color. The novel EC device achieved both representations of chromatic color and retained its color without power supply.
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spelling doaj.art-9563ccfa2d0f4eada5fd89398055eb5c2023-01-02T17:23:22ZengThe Electrochemical Society of JapanElectrochemistry2186-24512022-04-0190404700204700210.5796/electrochemistry.22-00006electrochemistryCompensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic ColorShunsuke KIMURA0Hikaru WAKATSUKI1Kazuki NAKAMURA2Norihisa KOBAYASHI3Graduate School of Science and Engineering, Chiba UniversityGraduate School of Science and Engineering, Chiba UniversityGraduate School of Science and Engineering, Chiba UniversityGraduate School of Science and Engineering, Chiba UniversitySilver deposition-based electrochromic (EC) device enabled various optical states by using either the electrodeposition of silver thin films or silver nanoparticles on an indium tin oxide electrode. These optical states, including chromatic colors such as cyan, magenta, yellow, and green, are based on absorption by the localized surface plasmon resonance of silver nanoparticles. However, an ideal counter-reaction material that does not affect the color representation by silver nanoparticles and does not dissolve the deposited silver has not been reported. To achieve both color retention and chromatic color representation, MnO2 was utilized as the counter electrode material. The EC properties of the novel device with the MnO2 counter electrode were investigated in terms of charge density and its ability to change color. The novel EC device achieved both representations of chromatic color and retained its color without power supply.https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00006/_html/-char/enelectrochromismsilvermanganese oxidelocalized surface plasmon resonance (lspr)
spellingShingle Shunsuke KIMURA
Hikaru WAKATSUKI
Kazuki NAKAMURA
Norihisa KOBAYASHI
Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
Electrochemistry
electrochromism
silver
manganese oxide
localized surface plasmon resonance (lspr)
title Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
title_full Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
title_fullStr Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
title_full_unstemmed Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
title_short Compensative Electrochromic Device Utilizing Electro-deposited Plasmonic Silver Nanoparticles and Manganese Oxide to Achieve Retention of Chromatic Color
title_sort compensative electrochromic device utilizing electro deposited plasmonic silver nanoparticles and manganese oxide to achieve retention of chromatic color
topic electrochromism
silver
manganese oxide
localized surface plasmon resonance (lspr)
url https://www.jstage.jst.go.jp/article/electrochemistry/90/4/90_22-00006/_html/-char/en
work_keys_str_mv AT shunsukekimura compensativeelectrochromicdeviceutilizingelectrodepositedplasmonicsilvernanoparticlesandmanganeseoxidetoachieveretentionofchromaticcolor
AT hikaruwakatsuki compensativeelectrochromicdeviceutilizingelectrodepositedplasmonicsilvernanoparticlesandmanganeseoxidetoachieveretentionofchromaticcolor
AT kazukinakamura compensativeelectrochromicdeviceutilizingelectrodepositedplasmonicsilvernanoparticlesandmanganeseoxidetoachieveretentionofchromaticcolor
AT norihisakobayashi compensativeelectrochromicdeviceutilizingelectrodepositedplasmonicsilvernanoparticlesandmanganeseoxidetoachieveretentionofchromaticcolor