One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors

Ni-Co binary hydroxide grown on nickel foam was synthesized through a facile one-step process for pseudocapacitive electrode application. The morphology of the fabricated binary hydroxide, evolving from nanosheet to nanowire, was highly controllable by tuning the Ni:Co ratio. In systematical electro...

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Main Authors: Xiao Fan, Per Ohlckers, Xuyuan Chen
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/10/11/3814
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author Xiao Fan
Per Ohlckers
Xuyuan Chen
author_facet Xiao Fan
Per Ohlckers
Xuyuan Chen
author_sort Xiao Fan
collection DOAJ
description Ni-Co binary hydroxide grown on nickel foam was synthesized through a facile one-step process for pseudocapacitive electrode application. The morphology of the fabricated binary hydroxide, evolving from nanosheet to nanowire, was highly controllable by tuning the Ni:Co ratio. In systematical electrochemical measurements, the prepared binary material on nickel foam could be employed as a binder-free working electrode directly. The optimal composition obtained at the Ni:Co ratio of 5:5 in integrated nanosheet/nanowire geometry exhibited high specific capacitances of 2807 and 2222 F/g at current densities of 1 and 20 A/g, equivalent to excellent rate capability. The capacitance loss was 19.8% after 2000 cycles, demonstrating good long-term cyclic stability. The outstanding supercapacitors behaviors benefited from unique structure and synergistic contributions, indicating the great potential of the obtained binary hydroxide electrode for high-performance energy storage devices.
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spelling doaj.art-956651ccd802493394ddf5a5cbd8fcf32023-11-20T02:19:36ZengMDPI AGApplied Sciences2076-34172020-05-011011381410.3390/app10113814One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance SupercapacitorsXiao Fan0Per Ohlckers1Xuyuan Chen2Department of Microsystems, Faculty of Technology, Natural Sciences and Maritime Sciences, University of South-Eastern Norway, Campus Vestfold, Raveien 215, 3184 Borre, NorwayDepartment of Microsystems, Faculty of Technology, Natural Sciences and Maritime Sciences, University of South-Eastern Norway, Campus Vestfold, Raveien 215, 3184 Borre, NorwayDepartment of Microsystems, Faculty of Technology, Natural Sciences and Maritime Sciences, University of South-Eastern Norway, Campus Vestfold, Raveien 215, 3184 Borre, NorwayNi-Co binary hydroxide grown on nickel foam was synthesized through a facile one-step process for pseudocapacitive electrode application. The morphology of the fabricated binary hydroxide, evolving from nanosheet to nanowire, was highly controllable by tuning the Ni:Co ratio. In systematical electrochemical measurements, the prepared binary material on nickel foam could be employed as a binder-free working electrode directly. The optimal composition obtained at the Ni:Co ratio of 5:5 in integrated nanosheet/nanowire geometry exhibited high specific capacitances of 2807 and 2222 F/g at current densities of 1 and 20 A/g, equivalent to excellent rate capability. The capacitance loss was 19.8% after 2000 cycles, demonstrating good long-term cyclic stability. The outstanding supercapacitors behaviors benefited from unique structure and synergistic contributions, indicating the great potential of the obtained binary hydroxide electrode for high-performance energy storage devices.https://www.mdpi.com/2076-3417/10/11/3814Ni-Co binary hydroxideone-stepcontrollable morphologybinder-freesupercapacitorssynergistic contributions
spellingShingle Xiao Fan
Per Ohlckers
Xuyuan Chen
One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
Applied Sciences
Ni-Co binary hydroxide
one-step
controllable morphology
binder-free
supercapacitors
synergistic contributions
title One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
title_full One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
title_fullStr One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
title_full_unstemmed One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
title_short One-Step and Morphology-Controlled Synthesis of Ni-Co Binary Hydroxide on Nickel Foam for High-Performance Supercapacitors
title_sort one step and morphology controlled synthesis of ni co binary hydroxide on nickel foam for high performance supercapacitors
topic Ni-Co binary hydroxide
one-step
controllable morphology
binder-free
supercapacitors
synergistic contributions
url https://www.mdpi.com/2076-3417/10/11/3814
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