Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone

Complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 3-salicylidenehydrazono-2-indolinone were prepared. Their structure was established to be [MLCl].Cl by using elemental analysis and molar conductivity, as well as AA, FTIR, UV/VIS and 1H-NMR spectroscopic methods. The spectral studies indicated a s...

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Main Authors: VESNA VASIC, ZIVOJIN CAKIC, BLAGA C. RADOVANOVIC, SANDRA S. KONSTANTINOVIC
Format: Article
Language:English
Published: Serbian Chemical Society 2003-09-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.yu/HtDocs/SHD/Vol68/No8-9/V68-No8_9-05.pdf
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author VESNA VASIC
ZIVOJIN CAKIC
BLAGA C. RADOVANOVIC
SANDRA S. KONSTANTINOVIC
author_facet VESNA VASIC
ZIVOJIN CAKIC
BLAGA C. RADOVANOVIC
SANDRA S. KONSTANTINOVIC
author_sort VESNA VASIC
collection DOAJ
description Complexes of Co(II), Ni(II), Cu(II) and Zn(II) with 3-salicylidenehydrazono-2-indolinone were prepared. Their structure was established to be [MLCl].Cl by using elemental analysis and molar conductivity, as well as AA, FTIR, UV/VIS and 1H-NMR spectroscopic methods. The spectral studies indicated a square-planar geometry for the Ni(II) and Cu(II) complexes and a tetrahedral one for the Co(II) and Zn(II) complexes. The complexes were tested for antibacterial activity against Staphylococcus aureus, Enterococcus D, Proteus mirabilis, Escherichia coli, Bacillus anthracis, Pseudomonas aeruginosa and Candida albicans.
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spelling doaj.art-95c0f4099e114269b6dce02a21a676652022-12-22T00:25:58ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392003-09-01688-9641647Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinoneVESNA VASICZIVOJIN CAKICBLAGA C. RADOVANOVICSANDRA S. KONSTANTINOVICComplexes of Co(II), Ni(II), Cu(II) and Zn(II) with 3-salicylidenehydrazono-2-indolinone were prepared. Their structure was established to be [MLCl].Cl by using elemental analysis and molar conductivity, as well as AA, FTIR, UV/VIS and 1H-NMR spectroscopic methods. The spectral studies indicated a square-planar geometry for the Ni(II) and Cu(II) complexes and a tetrahedral one for the Co(II) and Zn(II) complexes. The complexes were tested for antibacterial activity against Staphylococcus aureus, Enterococcus D, Proteus mirabilis, Escherichia coli, Bacillus anthracis, Pseudomonas aeruginosa and Candida albicans.http://www.shd.org.yu/HtDocs/SHD/Vol68/No8-9/V68-No8_9-05.pdfisatinsalicylaldehydetransition metal complexesFTIRUV/VIS1H-NMRantibacterial activity
spellingShingle VESNA VASIC
ZIVOJIN CAKIC
BLAGA C. RADOVANOVIC
SANDRA S. KONSTANTINOVIC
Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
Journal of the Serbian Chemical Society
isatin
salicylaldehyde
transition metal complexes
FTIR
UV/VIS
1H-NMR
antibacterial activity
title Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
title_full Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
title_fullStr Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
title_full_unstemmed Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
title_short Synthesis and characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 3-salicylidenehydrazono-2-indolinone
title_sort synthesis and characterization of co ii ni ii cu ii and zn ii complexes with 3 salicylidenehydrazono 2 indolinone
topic isatin
salicylaldehyde
transition metal complexes
FTIR
UV/VIS
1H-NMR
antibacterial activity
url http://www.shd.org.yu/HtDocs/SHD/Vol68/No8-9/V68-No8_9-05.pdf
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