Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel

A novel net analyte signal standard addition method (NASSAM) is presented for the simultaneous determination of Cd2+ and Ni2+ in their mixture by differential pulse polarography. The method combines the advantages of the standard addition method with the net analyte signal concept, which enables the...

Full description

Bibliographic Details
Main Authors: KARIM ASADPOUR-ZEYNALI, MIR REZA MAJIDI, MASOUD TAHMASEBPOUR
Format: Article
Language:English
Published: Serbian Chemical Society 2009-07-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.shd.org.rs/JSCS/Vol74/No7/09_4262_3877.pdf
_version_ 1819139752942632960
author KARIM ASADPOUR-ZEYNALI
MIR REZA MAJIDI
MASOUD TAHMASEBPOUR
author_facet KARIM ASADPOUR-ZEYNALI
MIR REZA MAJIDI
MASOUD TAHMASEBPOUR
author_sort KARIM ASADPOUR-ZEYNALI
collection DOAJ
description A novel net analyte signal standard addition method (NASSAM) is presented for the simultaneous determination of Cd2+ and Ni2+ in their mixture by differential pulse polarography. The method combines the advantages of the standard addition method with the net analyte signal concept, which enables the extraction of information concerning a certain analyte from voltammograms of multi-component mixtures. This method has some advantages, such as: the use of a full voltammogram, realization in a single step, therefore it does not require calibration and prediction steps and only a few measurements are required for the determination. The simultaneous determination of Cd2+ and Ni2+ was performed in Britton–Robinson buffer (pH 2.87) and 0.40 M potassium thiocyanate solution.saturated with water were determined.
first_indexed 2024-12-22T11:27:40Z
format Article
id doaj.art-96043949615d496c845936f616b2a6cb
institution Directory Open Access Journal
issn 0352-5139
language English
last_indexed 2024-12-22T11:27:40Z
publishDate 2009-07-01
publisher Serbian Chemical Society
record_format Article
series Journal of the Serbian Chemical Society
spelling doaj.art-96043949615d496c845936f616b2a6cb2022-12-21T18:27:43ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392009-07-01747789799Net analyte signal standard addition method for the simultaneous determination of cadmium and nickelKARIM ASADPOUR-ZEYNALIMIR REZA MAJIDIMASOUD TAHMASEBPOURA novel net analyte signal standard addition method (NASSAM) is presented for the simultaneous determination of Cd2+ and Ni2+ in their mixture by differential pulse polarography. The method combines the advantages of the standard addition method with the net analyte signal concept, which enables the extraction of information concerning a certain analyte from voltammograms of multi-component mixtures. This method has some advantages, such as: the use of a full voltammogram, realization in a single step, therefore it does not require calibration and prediction steps and only a few measurements are required for the determination. The simultaneous determination of Cd2+ and Ni2+ was performed in Britton–Robinson buffer (pH 2.87) and 0.40 M potassium thiocyanate solution.saturated with water were determined.http://www.shd.org.rs/JSCS/Vol74/No7/09_4262_3877.pdfdifferential pulse polarographysimultaneous determinationnet analyte signalstandard addition method
spellingShingle KARIM ASADPOUR-ZEYNALI
MIR REZA MAJIDI
MASOUD TAHMASEBPOUR
Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
Journal of the Serbian Chemical Society
differential pulse polarography
simultaneous determination
net analyte signal
standard addition method
title Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
title_full Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
title_fullStr Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
title_full_unstemmed Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
title_short Net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
title_sort net analyte signal standard addition method for the simultaneous determination of cadmium and nickel
topic differential pulse polarography
simultaneous determination
net analyte signal
standard addition method
url http://www.shd.org.rs/JSCS/Vol74/No7/09_4262_3877.pdf
work_keys_str_mv AT karimasadpourzeynali netanalytesignalstandardadditionmethodforthesimultaneousdeterminationofcadmiumandnickel
AT mirrezamajidi netanalytesignalstandardadditionmethodforthesimultaneousdeterminationofcadmiumandnickel
AT masoudtahmasebpour netanalytesignalstandardadditionmethodforthesimultaneousdeterminationofcadmiumandnickel