Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing

This paper shows a straightforward method for printing multilayer composite capacitors with three dielectric layers on flexible substrates. As known from multilayer ceramic chip capacitors (MLCCs), it is possible to create a parallel connection of the layers without enlarging the needed area. Hence,...

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Main Authors: Timo Reinheimer, Viktoria Baumann, Joachim R. Binder
Format: Article
Language:English
Published: MDPI AG 2020-11-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/11/2302
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author Timo Reinheimer
Viktoria Baumann
Joachim R. Binder
author_facet Timo Reinheimer
Viktoria Baumann
Joachim R. Binder
author_sort Timo Reinheimer
collection DOAJ
description This paper shows a straightforward method for printing multilayer composite capacitors with three dielectric layers on flexible substrates. As known from multilayer ceramic chip capacitors (MLCCs), it is possible to create a parallel connection of the layers without enlarging the needed area. Hence, the overall capacitance is increased, as the capacitances of the single dielectric layers add up. To realize printed capacitors, a special ceramic/polymer composite ink is used. The ink consists of surface-modified Ba<sub>0.6</sub>Sr<sub>0.4</sub>TiO<sub>3</sub> (BST), a polymeric crosslinking agent and a thermal initiator, which allows an immediate polymerization of the ink, leading to very homogenous layers. The dielectric behavior of the capacitors is examined for each completed dielectric layer (via impedance spectroscopy) so that the changes with every following layer can be analyzed. It is demonstrated that the concept works, and capacitors with up to 3420 pF were realized (permittivity of ~40). However, it was also shown that the biggest challenge is the printing of the needed silver electrodes. They show a strong coffee stain effect, leading to thicker edge areas, which are difficult to overprint. Only with the help of printed supporting structures was it possible to lower the failure rate when printing thin dielectric layers.
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spelling doaj.art-960f3ad6945146da8788c58a974ad1442023-11-20T21:46:30ZengMDPI AGNanomaterials2079-49912020-11-011011230210.3390/nano10112302Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet PrintingTimo Reinheimer0Viktoria Baumann1Joachim R. Binder2Institute for Applied Materials, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyInstitute for Applied Materials, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyInstitute for Applied Materials, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, GermanyThis paper shows a straightforward method for printing multilayer composite capacitors with three dielectric layers on flexible substrates. As known from multilayer ceramic chip capacitors (MLCCs), it is possible to create a parallel connection of the layers without enlarging the needed area. Hence, the overall capacitance is increased, as the capacitances of the single dielectric layers add up. To realize printed capacitors, a special ceramic/polymer composite ink is used. The ink consists of surface-modified Ba<sub>0.6</sub>Sr<sub>0.4</sub>TiO<sub>3</sub> (BST), a polymeric crosslinking agent and a thermal initiator, which allows an immediate polymerization of the ink, leading to very homogenous layers. The dielectric behavior of the capacitors is examined for each completed dielectric layer (via impedance spectroscopy) so that the changes with every following layer can be analyzed. It is demonstrated that the concept works, and capacitors with up to 3420 pF were realized (permittivity of ~40). However, it was also shown that the biggest challenge is the printing of the needed silver electrodes. They show a strong coffee stain effect, leading to thicker edge areas, which are difficult to overprint. Only with the help of printed supporting structures was it possible to lower the failure rate when printing thin dielectric layers.https://www.mdpi.com/2079-4991/10/11/2302inkjet printingprinted capacitorsceramic/polymer compositesmultilayer
spellingShingle Timo Reinheimer
Viktoria Baumann
Joachim R. Binder
Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
Nanomaterials
inkjet printing
printed capacitors
ceramic/polymer composites
multilayer
title Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
title_full Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
title_fullStr Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
title_full_unstemmed Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
title_short Fabrication of Flexible Multilayer Composite Capacitors Using Inkjet Printing
title_sort fabrication of flexible multilayer composite capacitors using inkjet printing
topic inkjet printing
printed capacitors
ceramic/polymer composites
multilayer
url https://www.mdpi.com/2079-4991/10/11/2302
work_keys_str_mv AT timoreinheimer fabricationofflexiblemultilayercompositecapacitorsusinginkjetprinting
AT viktoriabaumann fabricationofflexiblemultilayercompositecapacitorsusinginkjetprinting
AT joachimrbinder fabricationofflexiblemultilayercompositecapacitorsusinginkjetprinting