4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline
The title compound, C26H25N3, crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813006326 |
| _version_ | 1818491515832369152 |
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| author | Mehmet Akkurt Frank R. Fronczek Shaaban K. Mohamed Avtandil H. Talybov Adel A. E. Marzouk Antar A. Abdelhamid |
| author_facet | Mehmet Akkurt Frank R. Fronczek Shaaban K. Mohamed Avtandil H. Talybov Adel A. E. Marzouk Antar A. Abdelhamid |
| author_sort | Mehmet Akkurt |
| collection | DOAJ |
| description | The title compound, C26H25N3, crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethylaniline systems in these pairs of molecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethylaniline fragments of molecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H...π interactions that link the molecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3). |
| first_indexed | 2024-12-10T17:32:03Z |
| format | Article |
| id | doaj.art-96324f9faaff4f9fa22cc3d27a8e35b0 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:32:03Z |
| publishDate | 2013-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-96324f9faaff4f9fa22cc3d27a8e35b02022-12-22T01:39:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694o527o52810.1107/S16005368130063264-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylanilineMehmet AkkurtFrank R. FronczekShaaban K. MohamedAvtandil H. TalybovAdel A. E. MarzoukAntar A. AbdelhamidThe title compound, C26H25N3, crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethylaniline systems in these pairs of molecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethylaniline fragments of molecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H...π interactions that link the molecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3).http://scripts.iucr.org/cgi-bin/paper?S1600536813006326 |
| spellingShingle | Mehmet Akkurt Frank R. Fronczek Shaaban K. Mohamed Avtandil H. Talybov Adel A. E. Marzouk Antar A. Abdelhamid 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline Acta Crystallographica Section E |
| title | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
| title_full | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
| title_fullStr | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
| title_full_unstemmed | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
| title_short | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
| title_sort | 4 1 allyl 4 5 diphenyl 1h imidazol 2 yl n n dimethylaniline |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813006326 |
| work_keys_str_mv | AT mehmetakkurt 41allyl45diphenyl1himidazol2ylnndimethylaniline AT frankrfronczek 41allyl45diphenyl1himidazol2ylnndimethylaniline AT shaabankmohamed 41allyl45diphenyl1himidazol2ylnndimethylaniline AT avtandilhtalybov 41allyl45diphenyl1himidazol2ylnndimethylaniline AT adelaemarzouk 41allyl45diphenyl1himidazol2ylnndimethylaniline AT antaraabdelhamid 41allyl45diphenyl1himidazol2ylnndimethylaniline |