Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries
Abstract In the applications of large-scale energy storage, aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost nature. However, carrier ions always exhibit huge hydrated radius in aqueous electrolyte, which brings difficulty to find su...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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SpringerOpen
2021-08-01
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| Series: | Nano-Micro Letters |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s40820-021-00700-9 |
| _version_ | 1819152082832195584 |
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| author | Chiwei Xu Zhengwei Yang Xikun Zhang Maoting Xia Huihui Yan Jing Li Haoxiang Yu Liyuan Zhang Jie Shu |
| author_facet | Chiwei Xu Zhengwei Yang Xikun Zhang Maoting Xia Huihui Yan Jing Li Haoxiang Yu Liyuan Zhang Jie Shu |
| author_sort | Chiwei Xu |
| collection | DOAJ |
| description | Abstract In the applications of large-scale energy storage, aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost nature. However, carrier ions always exhibit huge hydrated radius in aqueous electrolyte, which brings difficulty to find suitable host materials that can achieve highly reversible insertion and extraction of cations. Owing to open three-dimensional rigid framework and facile synthesis, Prussian blue analogues (PBAs) receive the most extensive attention among various host candidates in aqueous system. Herein, a comprehensive review on recent progresses of PBAs in aqueous batteries is presented. Based on the application in different aqueous systems, the relationship between electrochemical behaviors (redox potential, capacity, cycling stability and rate performance) and structural characteristics (preparation method, structure type, particle size, morphology, crystallinity, defect, metal atom in high-spin state and chemical composition) is analyzed and summarized thoroughly. It can be concluded that the required type of PBAs is different for various carrier ions. In particular, the desalination batteries worked with the same mechanism as aqueous batteries are also discussed in detail to introduce the application of PBAs in aqueous systems comprehensively. This report can help the readers to understand the relationship between physical/chemical characteristics and electrochemical properties for PBAs and find a way to fabricate high-performance PBAs in aqueous batteries and desalination batteries. |
| first_indexed | 2024-12-22T14:43:39Z |
| format | Article |
| id | doaj.art-963403e0e60b4e4684d97b943f4c69f4 |
| institution | Directory Open Access Journal |
| issn | 2311-6706 2150-5551 |
| language | English |
| last_indexed | 2024-12-22T14:43:39Z |
| publishDate | 2021-08-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano-Micro Letters |
| spelling | doaj.art-963403e0e60b4e4684d97b943f4c69f42022-12-21T18:22:30ZengSpringerOpenNano-Micro Letters2311-67062150-55512021-08-0113113610.1007/s40820-021-00700-9Prussian Blue Analogues in Aqueous Batteries and Desalination BatteriesChiwei Xu0Zhengwei Yang1Xikun Zhang2Maoting Xia3Huihui Yan4Jing Li5Haoxiang Yu6Liyuan Zhang7Jie Shu8School of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversitySchool of Materials Science and Chemical Engineering, Ningbo UniversityAbstract In the applications of large-scale energy storage, aqueous batteries are considered as rivals for organic batteries due to their environmentally friendly and low-cost nature. However, carrier ions always exhibit huge hydrated radius in aqueous electrolyte, which brings difficulty to find suitable host materials that can achieve highly reversible insertion and extraction of cations. Owing to open three-dimensional rigid framework and facile synthesis, Prussian blue analogues (PBAs) receive the most extensive attention among various host candidates in aqueous system. Herein, a comprehensive review on recent progresses of PBAs in aqueous batteries is presented. Based on the application in different aqueous systems, the relationship between electrochemical behaviors (redox potential, capacity, cycling stability and rate performance) and structural characteristics (preparation method, structure type, particle size, morphology, crystallinity, defect, metal atom in high-spin state and chemical composition) is analyzed and summarized thoroughly. It can be concluded that the required type of PBAs is different for various carrier ions. In particular, the desalination batteries worked with the same mechanism as aqueous batteries are also discussed in detail to introduce the application of PBAs in aqueous systems comprehensively. This report can help the readers to understand the relationship between physical/chemical characteristics and electrochemical properties for PBAs and find a way to fabricate high-performance PBAs in aqueous batteries and desalination batteries.https://doi.org/10.1007/s40820-021-00700-9Prussian blue analoguesElectrochemistryCathodeAqueous batteriesDesalination batteries |
| spellingShingle | Chiwei Xu Zhengwei Yang Xikun Zhang Maoting Xia Huihui Yan Jing Li Haoxiang Yu Liyuan Zhang Jie Shu Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries Nano-Micro Letters Prussian blue analogues Electrochemistry Cathode Aqueous batteries Desalination batteries |
| title | Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries |
| title_full | Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries |
| title_fullStr | Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries |
| title_full_unstemmed | Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries |
| title_short | Prussian Blue Analogues in Aqueous Batteries and Desalination Batteries |
| title_sort | prussian blue analogues in aqueous batteries and desalination batteries |
| topic | Prussian blue analogues Electrochemistry Cathode Aqueous batteries Desalination batteries |
| url | https://doi.org/10.1007/s40820-021-00700-9 |
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