Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station

We present a modified retrieval strategy for solar absorption spectra recorded by the Karlsruhe Fourier Transform Infrared (FTIR) spectrometer, which is operational within the Total Carbon Column Observing Network (TCCON). In typical TCCON stations, the 3800&ndash;11 000 cm<sup>&minu...

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Main Authors: M. Kiel, D. Wunch, P. O. Wennberg, G. C. Toon, F. Hase, T. Blumenstock
Format: Article
Language:English
Published: Copernicus Publications 2016-02-01
Series:Atmospheric Measurement Techniques
Online Access:http://www.atmos-meas-tech.net/9/669/2016/amt-9-669-2016.pdf
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author M. Kiel
D. Wunch
P. O. Wennberg
G. C. Toon
F. Hase
T. Blumenstock
author_facet M. Kiel
D. Wunch
P. O. Wennberg
G. C. Toon
F. Hase
T. Blumenstock
author_sort M. Kiel
collection DOAJ
description We present a modified retrieval strategy for solar absorption spectra recorded by the Karlsruhe Fourier Transform Infrared (FTIR) spectrometer, which is operational within the Total Carbon Column Observing Network (TCCON). In typical TCCON stations, the 3800&ndash;11 000 cm<sup>&minus;1</sup> spectral region is measured on a single extended Indium Gallium Arsenide (InGaAs) detector. The Karlsruhe setup instead splits the spectrum across an Indium Antimonide (InSb) and InGaAs detector through the use of a dichroic beam splitter. This permits measurements further into the mid-infrared (MIR) that are of scientific interest, but are not considered TCCON measurements. This optical setup induces, however, larger variations in the continuum level of the solar spectra than the typical TCCON setup. Here we investigate the appropriate treatment of continuum-level variations in the retrieval strategy using the spectra recorded in Karlsruhe. The broad spectral windows used by TCCON require special attention with respect to residual curvature in the spectral fits. To accommodate the unique setup of Karlsruhe, higher-order discrete Legendre polynomial basis functions have been enabled in the TCCON retrieval code to fit the continuum. This improves spectral fits and air-mass dependencies for affected spectral windows. After fitting the continuum curvature, the Karlsruhe greenhouse gas records are in good agreement with other European TCCON data sets.
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spelling doaj.art-9648cd89031d468c9f8ddc238b3f7eeb2022-12-22T03:33:53ZengCopernicus PublicationsAtmospheric Measurement Techniques1867-13811867-85482016-02-019266968210.5194/amt-9-669-2016Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON stationM. Kiel0D. Wunch1P. O. Wennberg2G. C. Toon3F. Hase4T. Blumenstock5Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, GermanyDepartment of Environmental Science and Engineering, California Institute of Technology, Pasadena, CA, USADepartment of Environmental Science and Engineering, California Institute of Technology, Pasadena, CA, USAJet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USAInstitute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, GermanyInstitute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, GermanyWe present a modified retrieval strategy for solar absorption spectra recorded by the Karlsruhe Fourier Transform Infrared (FTIR) spectrometer, which is operational within the Total Carbon Column Observing Network (TCCON). In typical TCCON stations, the 3800&ndash;11 000 cm<sup>&minus;1</sup> spectral region is measured on a single extended Indium Gallium Arsenide (InGaAs) detector. The Karlsruhe setup instead splits the spectrum across an Indium Antimonide (InSb) and InGaAs detector through the use of a dichroic beam splitter. This permits measurements further into the mid-infrared (MIR) that are of scientific interest, but are not considered TCCON measurements. This optical setup induces, however, larger variations in the continuum level of the solar spectra than the typical TCCON setup. Here we investigate the appropriate treatment of continuum-level variations in the retrieval strategy using the spectra recorded in Karlsruhe. The broad spectral windows used by TCCON require special attention with respect to residual curvature in the spectral fits. To accommodate the unique setup of Karlsruhe, higher-order discrete Legendre polynomial basis functions have been enabled in the TCCON retrieval code to fit the continuum. This improves spectral fits and air-mass dependencies for affected spectral windows. After fitting the continuum curvature, the Karlsruhe greenhouse gas records are in good agreement with other European TCCON data sets.http://www.atmos-meas-tech.net/9/669/2016/amt-9-669-2016.pdf
spellingShingle M. Kiel
D. Wunch
P. O. Wennberg
G. C. Toon
F. Hase
T. Blumenstock
Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
Atmospheric Measurement Techniques
title Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
title_full Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
title_fullStr Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
title_full_unstemmed Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
title_short Improved retrieval of gas abundances from near-infrared solar FTIR spectra measured at the Karlsruhe TCCON station
title_sort improved retrieval of gas abundances from near infrared solar ftir spectra measured at the karlsruhe tccon station
url http://www.atmos-meas-tech.net/9/669/2016/amt-9-669-2016.pdf
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AT powennberg improvedretrievalofgasabundancesfromnearinfraredsolarftirspectrameasuredatthekarlsruhetcconstation
AT gctoon improvedretrievalofgasabundancesfromnearinfraredsolarftirspectrameasuredatthekarlsruhetcconstation
AT fhase improvedretrievalofgasabundancesfromnearinfraredsolarftirspectrameasuredatthekarlsruhetcconstation
AT tblumenstock improvedretrievalofgasabundancesfromnearinfraredsolarftirspectrameasuredatthekarlsruhetcconstation