Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes
The synthesis and isolation of uranium(VI) nitride complexes remains challenging. Here, the authors report an example of transition metal (TM) stabilized U(VI) nitride complexes, generated via photolysis of azide-bridged U(IV)-TM precursors.
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-07-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-31582-z |
| _version_ | 1811328278939566080 |
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| author | Xiaoqing Xin Iskander Douair Thayalan Rajeshkumar Yue Zhao Shuao Wang Laurent Maron Congqing Zhu |
| author_facet | Xiaoqing Xin Iskander Douair Thayalan Rajeshkumar Yue Zhao Shuao Wang Laurent Maron Congqing Zhu |
| author_sort | Xiaoqing Xin |
| collection | DOAJ |
| description | The synthesis and isolation of uranium(VI) nitride complexes remains challenging. Here, the authors report an example of transition metal (TM) stabilized U(VI) nitride complexes, generated via photolysis of azide-bridged U(IV)-TM precursors. |
| first_indexed | 2024-04-13T15:23:30Z |
| format | Article |
| id | doaj.art-965210c08c66401b8ba2c859ca26eafb |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-04-13T15:23:30Z |
| publishDate | 2022-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-965210c08c66401b8ba2c859ca26eafb2022-12-22T02:41:35ZengNature PortfolioNature Communications2041-17232022-07-011311910.1038/s41467-022-31582-zPhotochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride ComplexesXiaoqing Xin0Iskander Douair1Thayalan Rajeshkumar2Yue Zhao3Shuao Wang4Laurent Maron5Congqing Zhu6State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityLPCNO, CNRS & INSA, Université Paul SabatierLPCNO, CNRS & INSA, Université Paul SabatierState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityState Key Laboratory of Radiation Medicine and Protection, School for Radiological and interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow UniversityLPCNO, CNRS & INSA, Université Paul SabatierState Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing UniversityThe synthesis and isolation of uranium(VI) nitride complexes remains challenging. Here, the authors report an example of transition metal (TM) stabilized U(VI) nitride complexes, generated via photolysis of azide-bridged U(IV)-TM precursors.https://doi.org/10.1038/s41467-022-31582-z |
| spellingShingle | Xiaoqing Xin Iskander Douair Thayalan Rajeshkumar Yue Zhao Shuao Wang Laurent Maron Congqing Zhu Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes Nature Communications |
| title | Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes |
| title_full | Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes |
| title_fullStr | Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes |
| title_full_unstemmed | Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes |
| title_short | Photochemical Synthesis of Transition Metal-Stabilized Uranium(VI) Nitride Complexes |
| title_sort | photochemical synthesis of transition metal stabilized uranium vi nitride complexes |
| url | https://doi.org/10.1038/s41467-022-31582-z |
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