Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell

Abstract In this study, we fabricate uniform silicon nanowire (SiNW) arrays on 6-inch mono- and multi-crystalline wafers by employing the improved solution-processed metal-assisted chemical etching (MacEtch) method. Furthermore, the improved MacEtch can be applied to various crystalline orientation...

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Main Authors: Chen-Chih Hsueh, Subramani Thiyagu, Chien-Ting Liu, Hong-Jhang Syu, Song-Ting Yang, Ching-Fuh Lin
Format: Article
Language:English
Published: SpringerOpen 2019-06-01
Series:Nanoscale Research Letters
Subjects:
Online Access:http://link.springer.com/article/10.1186/s11671-019-3030-y
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author Chen-Chih Hsueh
Subramani Thiyagu
Chien-Ting Liu
Hong-Jhang Syu
Song-Ting Yang
Ching-Fuh Lin
author_facet Chen-Chih Hsueh
Subramani Thiyagu
Chien-Ting Liu
Hong-Jhang Syu
Song-Ting Yang
Ching-Fuh Lin
author_sort Chen-Chih Hsueh
collection DOAJ
description Abstract In this study, we fabricate uniform silicon nanowire (SiNW) arrays on 6-inch mono- and multi-crystalline wafers by employing the improved solution-processed metal-assisted chemical etching (MacEtch) method. Furthermore, the improved MacEtch can be applied to various crystalline orientation wafers. The SiNW arrays are 470 nm in length with high density; they demonstrate a good optical trapping effect and reflectance well below 6% over a broad wavelength range from 300 to 1100 nm. The improved MacEtch shows no difference in reflectance for a pyramid/SiNW mono-crystalline wafer with appropriate uniformity; the average delta from the center to other positions is within 22%. The effective lifetime is lower for SiNW arrays because the higher surface state causes higher surface recombination. Finally, we make the multi-crystalline wafer into an Al-BSF solar cell device with MacEtch SiNW texture, resulting in an averaged power conversion efficiency of 17.83%, which is higher than that of standard acid-textured solar cell devices. Consequently, the improved MacEtch concept is suitable for commercial mass production in the photovoltaic industry.
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spelling doaj.art-966e6bfbf92f4b44b771a8ed2c81fd462023-09-02T23:15:45ZengSpringerOpenNanoscale Research Letters1931-75731556-276X2019-06-0114111210.1186/s11671-019-3030-yApplication of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar CellChen-Chih Hsueh0Subramani Thiyagu1Chien-Ting Liu2Hong-Jhang Syu3Song-Ting Yang4Ching-Fuh Lin5Graduate Institute of Photonics and Optoelectronics, National Taiwan UniversityGraduate Institute of Photonics and Optoelectronics, National Taiwan UniversityGraduate Institute of Photonics and Optoelectronics, National Taiwan UniversityGraduate Institute of Photonics and Optoelectronics, National Taiwan UniversityGraduate Institute of Electronics Engineering, National Taiwan UniversityGraduate Institute of Photonics and Optoelectronics, National Taiwan UniversityAbstract In this study, we fabricate uniform silicon nanowire (SiNW) arrays on 6-inch mono- and multi-crystalline wafers by employing the improved solution-processed metal-assisted chemical etching (MacEtch) method. Furthermore, the improved MacEtch can be applied to various crystalline orientation wafers. The SiNW arrays are 470 nm in length with high density; they demonstrate a good optical trapping effect and reflectance well below 6% over a broad wavelength range from 300 to 1100 nm. The improved MacEtch shows no difference in reflectance for a pyramid/SiNW mono-crystalline wafer with appropriate uniformity; the average delta from the center to other positions is within 22%. The effective lifetime is lower for SiNW arrays because the higher surface state causes higher surface recombination. Finally, we make the multi-crystalline wafer into an Al-BSF solar cell device with MacEtch SiNW texture, resulting in an averaged power conversion efficiency of 17.83%, which is higher than that of standard acid-textured solar cell devices. Consequently, the improved MacEtch concept is suitable for commercial mass production in the photovoltaic industry.http://link.springer.com/article/10.1186/s11671-019-3030-ySilicon nanowireMetal-assisted chemical etchingLow reflectanceSix-inch waferCarrier lifetime
spellingShingle Chen-Chih Hsueh
Subramani Thiyagu
Chien-Ting Liu
Hong-Jhang Syu
Song-Ting Yang
Ching-Fuh Lin
Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
Nanoscale Research Letters
Silicon nanowire
Metal-assisted chemical etching
Low reflectance
Six-inch wafer
Carrier lifetime
title Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
title_full Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
title_fullStr Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
title_full_unstemmed Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
title_short Application of Silicon Nanostructure Arrays for 6-inch Mono and Multi-Crystalline Solar Cell
title_sort application of silicon nanostructure arrays for 6 inch mono and multi crystalline solar cell
topic Silicon nanowire
Metal-assisted chemical etching
Low reflectance
Six-inch wafer
Carrier lifetime
url http://link.springer.com/article/10.1186/s11671-019-3030-y
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