Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells
New donor–π–acceptor pyrimidine-based dyes comprising an amide moiety as an anchoring group have been designed. The dyes were synthesized by sequential procedures based on the microwave-assisted Suzuki cross-coupling and bromination reactions. The influence of the dye structure and length of π-linke...
| Main Authors: | , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2021-05-01
|
| Series: | Electronic Materials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2673-3978/2/2/12 |
| _version_ | 1797528079924461568 |
|---|---|
| author | Egor V. Verbitskiy Alexander S. Steparuk Ekaterina F. Zhilina Viktor V. Emets Vitaly A. Grinberg Ekaterina V. Krivogina Sergey A. Kozyukhin Ekaterina V. Belova Petr I. Lazarenko Gennady L. Rusinov Alexey R. Tameev Jean Michel Nunzi Valery N. Charushin |
| author_facet | Egor V. Verbitskiy Alexander S. Steparuk Ekaterina F. Zhilina Viktor V. Emets Vitaly A. Grinberg Ekaterina V. Krivogina Sergey A. Kozyukhin Ekaterina V. Belova Petr I. Lazarenko Gennady L. Rusinov Alexey R. Tameev Jean Michel Nunzi Valery N. Charushin |
| author_sort | Egor V. Verbitskiy |
| collection | DOAJ |
| description | New donor–π–acceptor pyrimidine-based dyes comprising an amide moiety as an anchoring group have been designed. The dyes were synthesized by sequential procedures based on the microwave-assisted Suzuki cross-coupling and bromination reactions. The influence of the dye structure and length of π-linker on the photophysical and electrochemical properties and on the photovoltaic effectiveness of dye-sensitized solar cells was investigated. An increase in efficiency with a decrease in the length of π-linker was revealed. The <b>D1</b> dye with only one 2,5-thienylene-linker provided the highest power conversion efficiency among the fabricated dye sensitized solar cells. |
| first_indexed | 2024-03-10T09:53:01Z |
| format | Article |
| id | doaj.art-96755225ce3942958be562f411178be2 |
| institution | Directory Open Access Journal |
| issn | 2673-3978 |
| language | English |
| last_indexed | 2024-03-10T09:53:01Z |
| publishDate | 2021-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Electronic Materials |
| spelling | doaj.art-96755225ce3942958be562f411178be22023-11-22T02:37:11ZengMDPI AGElectronic Materials2673-39782021-05-012214215310.3390/electronicmat2020012Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar CellsEgor V. Verbitskiy0Alexander S. Steparuk1Ekaterina F. Zhilina2Viktor V. Emets3Vitaly A. Grinberg4Ekaterina V. Krivogina5Sergey A. Kozyukhin6Ekaterina V. Belova7Petr I. Lazarenko8Gennady L. Rusinov9Alexey R. Tameev10Jean Michel Nunzi11Valery N. Charushin12I. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., 22, 620108 Ekaterinburg, RussiaI. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., 22, 620108 Ekaterinburg, RussiaI. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., 22, 620108 Ekaterinburg, RussiaA. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaA. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaN. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31, Leninsky Pr., 119991 Moscow, RussiaN. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31, Leninsky Pr., 119991 Moscow, RussiaDepartment of Chemistry, Moscow State University, 119991 Moscow, RussiaInstitute of Advanced Materials and Technologies, National Research University of Electronic Technology, 124498 Moscow, RussiaI. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., 22, 620108 Ekaterinburg, RussiaA. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, RussiaNanomaterials Research Institute, Kanazawa University, Kanazawa 920-1192, JapanI. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., 22, 620108 Ekaterinburg, RussiaNew donor–π–acceptor pyrimidine-based dyes comprising an amide moiety as an anchoring group have been designed. The dyes were synthesized by sequential procedures based on the microwave-assisted Suzuki cross-coupling and bromination reactions. The influence of the dye structure and length of π-linker on the photophysical and electrochemical properties and on the photovoltaic effectiveness of dye-sensitized solar cells was investigated. An increase in efficiency with a decrease in the length of π-linker was revealed. The <b>D1</b> dye with only one 2,5-thienylene-linker provided the highest power conversion efficiency among the fabricated dye sensitized solar cells.https://www.mdpi.com/2673-3978/2/2/12pyrimidinetriphenylamineamide groupdye-sensitized solar cells |
| spellingShingle | Egor V. Verbitskiy Alexander S. Steparuk Ekaterina F. Zhilina Viktor V. Emets Vitaly A. Grinberg Ekaterina V. Krivogina Sergey A. Kozyukhin Ekaterina V. Belova Petr I. Lazarenko Gennady L. Rusinov Alexey R. Tameev Jean Michel Nunzi Valery N. Charushin Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells Electronic Materials pyrimidine triphenylamine amide group dye-sensitized solar cells |
| title | Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells |
| title_full | Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells |
| title_fullStr | Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells |
| title_full_unstemmed | Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells |
| title_short | Pyrimidine-Based Push–Pull Systems with a New Anchoring Amide Group for Dye-Sensitized Solar Cells |
| title_sort | pyrimidine based push pull systems with a new anchoring amide group for dye sensitized solar cells |
| topic | pyrimidine triphenylamine amide group dye-sensitized solar cells |
| url | https://www.mdpi.com/2673-3978/2/2/12 |
| work_keys_str_mv | AT egorvverbitskiy pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT alexanderssteparuk pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT ekaterinafzhilina pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT viktorvemets pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT vitalyagrinberg pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT ekaterinavkrivogina pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT sergeyakozyukhin pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT ekaterinavbelova pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT petrilazarenko pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT gennadylrusinov pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT alexeyrtameev pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT jeanmichelnunzi pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells AT valeryncharushin pyrimidinebasedpushpullsystemswithanewanchoringamidegroupfordyesensitizedsolarcells |