Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation

The performance of Cu-Fe alloy is related to the solidification structure, which is directly determined by the microstructure evolution during solidification. The solidification sequence, solid–liquid interface variation, and microstructural evolution of Cu-20wt%Fe alloy at three cooling rates (0.3,...

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Main Authors: Junli Guo, Deping Lu, Jin Zou
Format: Article
Language:English
Published: MDPI AG 2023-03-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/3/581
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author Junli Guo
Deping Lu
Jin Zou
author_facet Junli Guo
Deping Lu
Jin Zou
author_sort Junli Guo
collection DOAJ
description The performance of Cu-Fe alloy is related to the solidification structure, which is directly determined by the microstructure evolution during solidification. The solidification sequence, solid–liquid interface variation, and microstructural evolution of Cu-20wt%Fe alloy at three cooling rates (0.3, 1.5, and 5.0 °C/s) were investigated. The results indicate that the remelting of primary γ-Fe dendrites was directly observed through the solidification experiment, and the partial γ-Fe dendrite was fragmented owing to remelting. The Fe phase morphology changed from the cellular structure to the typical finer and longer dendrite structure with the cooling rate increasing. As the cooling rate increased, the constitutional undercooling caused by the decrease in the Fe atom concentration and the increase in the Cu atom concentration increased in the solidifying interface. There was a parabolic relationship between the growth rate of the dendrite tip and time. Meanwhile, the growth of the primary γ-Fe phase was inhibited by the insufficient diffusion of Fe and Cu at the solidification front, which resulted in a decrease in the Fe phase volume fraction, and the Fe content in the Fe dendritic phase decreased slightly.
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spelling doaj.art-967719e4bc4b4b8396cdd78d217b4d102023-11-17T12:39:45ZengMDPI AGMetals2075-47012023-03-0113358110.3390/met13030581Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ ObservationJunli Guo0Deping Lu1Jin Zou2Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330098, ChinaInstitute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330098, ChinaInstitute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330098, ChinaThe performance of Cu-Fe alloy is related to the solidification structure, which is directly determined by the microstructure evolution during solidification. The solidification sequence, solid–liquid interface variation, and microstructural evolution of Cu-20wt%Fe alloy at three cooling rates (0.3, 1.5, and 5.0 °C/s) were investigated. The results indicate that the remelting of primary γ-Fe dendrites was directly observed through the solidification experiment, and the partial γ-Fe dendrite was fragmented owing to remelting. The Fe phase morphology changed from the cellular structure to the typical finer and longer dendrite structure with the cooling rate increasing. As the cooling rate increased, the constitutional undercooling caused by the decrease in the Fe atom concentration and the increase in the Cu atom concentration increased in the solidifying interface. There was a parabolic relationship between the growth rate of the dendrite tip and time. Meanwhile, the growth of the primary γ-Fe phase was inhibited by the insufficient diffusion of Fe and Cu at the solidification front, which resulted in a decrease in the Fe phase volume fraction, and the Fe content in the Fe dendritic phase decreased slightly.https://www.mdpi.com/2075-4701/13/3/581copper iron alloysolidificationin situ observationcooling rates
spellingShingle Junli Guo
Deping Lu
Jin Zou
Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
Metals
copper iron alloy
solidification
in situ observation
cooling rates
title Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
title_full Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
title_fullStr Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
title_full_unstemmed Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
title_short Investigation on Solidification in Cu-20wt%Fe Alloy through In Situ Observation
title_sort investigation on solidification in cu 20wt fe alloy through in situ observation
topic copper iron alloy
solidification
in situ observation
cooling rates
url https://www.mdpi.com/2075-4701/13/3/581
work_keys_str_mv AT junliguo investigationonsolidificationincu20wtfealloythroughinsituobservation
AT depinglu investigationonsolidificationincu20wtfealloythroughinsituobservation
AT jinzou investigationonsolidificationincu20wtfealloythroughinsituobservation