Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids

Abstract Based on solutions of the Ornstein–Zernike equation (OZE) of Lennard–Jones potential for mean spherical approximation (MSA), we derive analytical formula for the compressibility assuming that the system is of low density, homogeneous, isotropic and composed of one component. Depending on th...

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Main Authors: Marwan Al-Raeei, Moustafa Sayem El-Daher
Format: Article
Language:English
Published: BMC 2020-08-01
Series:BMC Chemistry
Subjects:
Online Access:http://link.springer.com/article/10.1186/s13065-020-00702-5
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author Marwan Al-Raeei
Moustafa Sayem El-Daher
author_facet Marwan Al-Raeei
Moustafa Sayem El-Daher
author_sort Marwan Al-Raeei
collection DOAJ
description Abstract Based on solutions of the Ornstein–Zernike equation (OZE) of Lennard–Jones potential for mean spherical approximation (MSA), we derive analytical formula for the compressibility assuming that the system is of low density, homogeneous, isotropic and composed of one component. Depending on this formula, we find the values of the bulk modulus and the compressibility of air at room temperature and the bulk modulus and the compressibility of Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbon. Also, we find the speed of sound in the air at various temperatures, the speed of sound in each of Helium, Neon, Argon, Krypton, Xenon, Methane, Ethylene, Propylene, Propane, Hydrogen, Nitrogen, Fluorine, Chlorine, Oxygen, Nitrous oxide (laughing gas), Carbon dioxide, Nitric oxide, Carbon monoxide, Sulphur dioxide and dichlorodifluoromethane at room temperature. Besides, we find the speed of sound in Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbons depending on the formula we find. We show that the simple formula we derive in this work is reliable and agrees with the results obtained from other studies and literatures. We believe it can be used for many systems which are in low densities and described by Lennard–Jones potential.
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spelling doaj.art-9679da6c290c4f4494d29fd83cbd918f2022-12-22T00:59:28ZengBMCBMC Chemistry2661-801X2020-08-011411710.1186/s13065-020-00702-5Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluidsMarwan Al-Raeei0Moustafa Sayem El-Daher1Faculty of Sciences, Damascus UniversityFaculty of Informatics and Communications, Arab International UniversityAbstract Based on solutions of the Ornstein–Zernike equation (OZE) of Lennard–Jones potential for mean spherical approximation (MSA), we derive analytical formula for the compressibility assuming that the system is of low density, homogeneous, isotropic and composed of one component. Depending on this formula, we find the values of the bulk modulus and the compressibility of air at room temperature and the bulk modulus and the compressibility of Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbon. Also, we find the speed of sound in the air at various temperatures, the speed of sound in each of Helium, Neon, Argon, Krypton, Xenon, Methane, Ethylene, Propylene, Propane, Hydrogen, Nitrogen, Fluorine, Chlorine, Oxygen, Nitrous oxide (laughing gas), Carbon dioxide, Nitric oxide, Carbon monoxide, Sulphur dioxide and dichlorodifluoromethane at room temperature. Besides, we find the speed of sound in Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbons depending on the formula we find. We show that the simple formula we derive in this work is reliable and agrees with the results obtained from other studies and literatures. We believe it can be used for many systems which are in low densities and described by Lennard–Jones potential.http://link.springer.com/article/10.1186/s13065-020-00702-5CompressibilityLenard–Jones potentialBulk modulusOne component fluidBulk modulusStatic structure factor
spellingShingle Marwan Al-Raeei
Moustafa Sayem El-Daher
Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
BMC Chemistry
Compressibility
Lenard–Jones potential
Bulk modulus
One component fluid
Bulk modulus
Static structure factor
title Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
title_full Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
title_fullStr Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
title_full_unstemmed Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
title_short Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids
title_sort formula of compressibility and using it for air noble gases some hydrocarbons gases some diatomic simple gases and some other fluids
topic Compressibility
Lenard–Jones potential
Bulk modulus
One component fluid
Bulk modulus
Static structure factor
url http://link.springer.com/article/10.1186/s13065-020-00702-5
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