Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland)
Geochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemica...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2009-12-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.rs/JSCS/Vol74/No12/13_4378_3934.pdf |
| _version_ | 1818145365676785664 |
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| author | NENAD S. KRSTIĆ DRAGAN M. DJORDJEVIĆ BRATISLAV Ž. TODOROVIĆ JUSTYNA CIESIELCZUK PAVLE I. PREMOVIĆ |
| author_facet | NENAD S. KRSTIĆ DRAGAN M. DJORDJEVIĆ BRATISLAV Ž. TODOROVIĆ JUSTYNA CIESIELCZUK PAVLE I. PREMOVIĆ |
| author_sort | NENAD S. KRSTIĆ |
| collection | DOAJ |
| description | Geochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemical fractionation and inductively coupled plasma–optical emission spectrometry indicated that most of the Fe (ca. 97 wt. % of the total metal) resides in the dickite. Electron spin resonance showed that some of the Fe in the dickite structure is in the form of Fe3+. A substantial proportion of these ions (as well as Fe) in the dickite matrix were probably contained in the original hydrothermal dickite-forming solution. From the geochemistry of Fe3+, it was deduced that the oxidation potential (Eh) and pH of the solution during the formation of dickite from the Jedlina Zdroj were approximately 0.45–0.95 V (highly oxygenated) and 0–4 (highly acidic), respectively. |
| first_indexed | 2024-12-11T12:02:18Z |
| format | Article |
| id | doaj.art-967f4d5c43084cc9a7779a8a07cfc970 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-11T12:02:18Z |
| publishDate | 2009-12-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-967f4d5c43084cc9a7779a8a07cfc9702022-12-22T01:08:03ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392009-12-01741214771489Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland)NENAD S. KRSTIĆDRAGAN M. DJORDJEVIĆBRATISLAV Ž. TODOROVIĆJUSTYNA CIESIELCZUKPAVLE I. PREMOVIĆGeochemical analysis for Fe was made on a representative sample of dickite-rich hydrothermal clay from Jedlina Zdroj. The mineralogy of the sample is comparatively simple, dickite being the principal component (>95 wt. % of the total sample), with lesser amounts of goethite and barite. Geochemical fractionation and inductively coupled plasma–optical emission spectrometry indicated that most of the Fe (ca. 97 wt. % of the total metal) resides in the dickite. Electron spin resonance showed that some of the Fe in the dickite structure is in the form of Fe3+. A substantial proportion of these ions (as well as Fe) in the dickite matrix were probably contained in the original hydrothermal dickite-forming solution. From the geochemistry of Fe3+, it was deduced that the oxidation potential (Eh) and pH of the solution during the formation of dickite from the Jedlina Zdroj were approximately 0.45–0.95 V (highly oxygenated) and 0–4 (highly acidic), respectively.http://www.shd.org.rs/JSCS/Vol74/No12/13_4378_3934.pdfkaolinitedickiteiron |
| spellingShingle | NENAD S. KRSTIĆ DRAGAN M. DJORDJEVIĆ BRATISLAV Ž. TODOROVIĆ JUSTYNA CIESIELCZUK PAVLE I. PREMOVIĆ Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) Journal of the Serbian Chemical Society kaolinite dickite iron |
| title | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_full | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_fullStr | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_full_unstemmed | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_short | Geochemistry of Fe3+ in the hydrothermal dickite from Jedlina Zdroj (Lower Silesia, Poland) |
| title_sort | geochemistry of fe3 in the hydrothermal dickite from jedlina zdroj lower silesia poland |
| topic | kaolinite dickite iron |
| url | http://www.shd.org.rs/JSCS/Vol74/No12/13_4378_3934.pdf |
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