Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans

Abstract During the Late Cretaceous, Earth's climate oscillated between warm and cool states, and global oceans changed between anoxic and oxic conditions, resulting in black/gray shales and oceanic red beds (ORBs) deposition, respectively. To understand such climate/ocean dynamics, this study...

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Main Authors: Ruiyang Sun, Hanwei Yao, Changzhou Deng, Stephen E. Grasby, Chengshan Wang, Xi Chen, Runsheng Yin
Format: Article
Language:English
Published: Wiley 2022-04-01
Series:Geochemistry, Geophysics, Geosystems
Subjects:
Online Access:https://doi.org/10.1029/2021GC010292
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author Ruiyang Sun
Hanwei Yao
Changzhou Deng
Stephen E. Grasby
Chengshan Wang
Xi Chen
Runsheng Yin
author_facet Ruiyang Sun
Hanwei Yao
Changzhou Deng
Stephen E. Grasby
Chengshan Wang
Xi Chen
Runsheng Yin
author_sort Ruiyang Sun
collection DOAJ
description Abstract During the Late Cretaceous, Earth's climate oscillated between warm and cool states, and global oceans changed between anoxic and oxic conditions, resulting in black/gray shales and oceanic red beds (ORBs) deposition, respectively. To understand such climate/ocean dynamics, this study investigated bulk Hg and Hg isotopes, as well as Fe3+/Fe2+ in Upper Cretaceous sediments deposited in southern Tibet and the North Atlantic. In both areas, black/gray shales show much higher Hg concentrations than ORBs, indicating enhanced Hg flux to global oceans during time of black/gray shale deposition. Black/gray shales show lower Fe3+/Fe2+ and positive Δ199Hg, suggesting a significant input of Hg into the anoxic/dysoxic ocean via atmospheric deposition. The isotope values are consistent with a volcanic source for this excess Hg. ORBs show high Fe3+/Fe2+ and negative shifts of Δ199Hg, suggesting that the dominant source of Hg into the oxic oceans was via terrestrial runoff. This study suggests that volcanism was an important driver of the climate/ocean dynamics during the Late Cretaceous.
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spelling doaj.art-96a4c39b59f04809999e58fc37ff9dea2023-11-03T16:56:16ZengWileyGeochemistry, Geophysics, Geosystems1525-20272022-04-01234n/an/a10.1029/2021GC010292Volcanism‐Triggered Climatic Control on Late Cretaceous OceansRuiyang Sun0Hanwei Yao1Changzhou Deng2Stephen E. Grasby3Chengshan Wang4Xi Chen5Runsheng Yin6State Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaState Key Laboratory of Biogeology and Environmental Geology China University of Geosciences Beijing ChinaState Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaGeological Survey of Canada, Calgary Natural Resources Canada Calgary AB CanadaState Key Laboratory of Biogeology and Environmental Geology China University of Geosciences Beijing ChinaState Key Laboratory of Biogeology and Environmental Geology China University of Geosciences Beijing ChinaState Key Laboratory of Ore Deposit Geochemistry Institute of Geochemistry Chinese Academy of Sciences Guiyang ChinaAbstract During the Late Cretaceous, Earth's climate oscillated between warm and cool states, and global oceans changed between anoxic and oxic conditions, resulting in black/gray shales and oceanic red beds (ORBs) deposition, respectively. To understand such climate/ocean dynamics, this study investigated bulk Hg and Hg isotopes, as well as Fe3+/Fe2+ in Upper Cretaceous sediments deposited in southern Tibet and the North Atlantic. In both areas, black/gray shales show much higher Hg concentrations than ORBs, indicating enhanced Hg flux to global oceans during time of black/gray shale deposition. Black/gray shales show lower Fe3+/Fe2+ and positive Δ199Hg, suggesting a significant input of Hg into the anoxic/dysoxic ocean via atmospheric deposition. The isotope values are consistent with a volcanic source for this excess Hg. ORBs show high Fe3+/Fe2+ and negative shifts of Δ199Hg, suggesting that the dominant source of Hg into the oxic oceans was via terrestrial runoff. This study suggests that volcanism was an important driver of the climate/ocean dynamics during the Late Cretaceous.https://doi.org/10.1029/2021GC010292mercuryLate Cretaceousvolcanismclimate/ocean dynamicsblack shaleoceanic red beds
spellingShingle Ruiyang Sun
Hanwei Yao
Changzhou Deng
Stephen E. Grasby
Chengshan Wang
Xi Chen
Runsheng Yin
Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
Geochemistry, Geophysics, Geosystems
mercury
Late Cretaceous
volcanism
climate/ocean dynamics
black shale
oceanic red beds
title Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
title_full Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
title_fullStr Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
title_full_unstemmed Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
title_short Volcanism‐Triggered Climatic Control on Late Cretaceous Oceans
title_sort volcanism triggered climatic control on late cretaceous oceans
topic mercury
Late Cretaceous
volcanism
climate/ocean dynamics
black shale
oceanic red beds
url https://doi.org/10.1029/2021GC010292
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AT changzhoudeng volcanismtriggeredclimaticcontrolonlatecretaceousoceans
AT stephenegrasby volcanismtriggeredclimaticcontrolonlatecretaceousoceans
AT chengshanwang volcanismtriggeredclimaticcontrolonlatecretaceousoceans
AT xichen volcanismtriggeredclimaticcontrolonlatecretaceousoceans
AT runshengyin volcanismtriggeredclimaticcontrolonlatecretaceousoceans