A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex
A new molecular conductor of (TMTSF)<sub>5</sub>[Dy(NCS)<sub>4</sub>(NO<sub>3</sub>)<sub>2</sub>]CHCl<sub>3</sub> was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc2<sub>1</sub> (36) spa...
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| Format: | Article |
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MDPI AG
2023-03-01
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| Series: | Magnetochemistry |
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| Online Access: | https://www.mdpi.com/2312-7481/9/3/77 |
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| author | Qingyun Wan Masanori Wakizaka Haitao Zhang Yongbing Shen Nobuto Funakoshi Chi-Ming Che Shinya Takaishi Masahiro Yamashita |
| author_facet | Qingyun Wan Masanori Wakizaka Haitao Zhang Yongbing Shen Nobuto Funakoshi Chi-Ming Che Shinya Takaishi Masahiro Yamashita |
| author_sort | Qingyun Wan |
| collection | DOAJ |
| description | A new molecular conductor of (TMTSF)<sub>5</sub>[Dy(NCS)<sub>4</sub>(NO<sub>3</sub>)<sub>2</sub>]CHCl<sub>3</sub> was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc2<sub>1</sub> (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm<sup>−1</sup> and an activation energy of 34 meV at ambient pressure. |
| first_indexed | 2024-03-11T06:16:27Z |
| format | Article |
| id | doaj.art-96aa28f23f124dd9868a33b638aa6669 |
| institution | Directory Open Access Journal |
| issn | 2312-7481 |
| language | English |
| last_indexed | 2024-03-11T06:16:27Z |
| publishDate | 2023-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Magnetochemistry |
| spelling | doaj.art-96aa28f23f124dd9868a33b638aa66692023-11-17T12:16:35ZengMDPI AGMagnetochemistry2312-74812023-03-01937710.3390/magnetochemistry9030077A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) ComplexQingyun Wan0Masanori Wakizaka1Haitao Zhang2Yongbing Shen3Nobuto Funakoshi4Chi-Ming Che5Shinya Takaishi6Masahiro Yamashita7Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanFrontier Institute of Science and Technology (FIST), State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis of Condensed Matter, Xi’an Jiaotong University, 99 Yanxiang Road, Xi’an 710054, ChinaDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanDepartment of Chemistry, State Key Laboratory of Synthetic Chemistry, HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, ChinaDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanDepartment of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, JapanA new molecular conductor of (TMTSF)<sub>5</sub>[Dy(NCS)<sub>4</sub>(NO<sub>3</sub>)<sub>2</sub>]CHCl<sub>3</sub> was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc2<sub>1</sub> (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm<sup>−1</sup> and an activation energy of 34 meV at ambient pressure.https://www.mdpi.com/2312-7481/9/3/77organic conductorelectro-crystallizationDysprosium(III)TMTSF |
| spellingShingle | Qingyun Wan Masanori Wakizaka Haitao Zhang Yongbing Shen Nobuto Funakoshi Chi-Ming Che Shinya Takaishi Masahiro Yamashita A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex Magnetochemistry organic conductor electro-crystallization Dysprosium(III) TMTSF |
| title | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
| title_full | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
| title_fullStr | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
| title_full_unstemmed | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
| title_short | A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex |
| title_sort | new organic conductor of tetramethyltetraselenafulvalene tmtsf with a magnetic dy iii complex |
| topic | organic conductor electro-crystallization Dysprosium(III) TMTSF |
| url | https://www.mdpi.com/2312-7481/9/3/77 |
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