Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]

In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni2(N3)4(C12H12N2)2], the NiII atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal ge...

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Main Author: Jin Hou
Format: Article
Language:English
Published: International Union of Crystallography 2008-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808037902
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author Jin Hou
author_facet Jin Hou
author_sort Jin Hou
collection DOAJ
description In the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni2(N3)4(C12H12N2)2], the NiII atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal geometry. The Ni...Ni distance is 3.2398 (12) Å.
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spelling doaj.art-96e9ca4b178d4eac98a4de3619cddcae2022-12-21T17:17:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1571m157110.1107/S1600536808037902Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]Jin HouIn the title azide-bridged dinuclear centrosymmetric nickel(II) complex, [Ni2(N3)4(C12H12N2)2], the NiII atom is five-coordinated by two N atoms of the 5,5′-dimethyl-2,2′-bipyridine ligand and three N atoms from three azide ligands in a distorted trigonal–bipyramidal geometry. The Ni...Ni distance is 3.2398 (12) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808037902
spellingShingle Jin Hou
Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
Acta Crystallographica Section E
title Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_full Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_fullStr Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_full_unstemmed Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_short Di-μ1,1-azido-bis[azido(5,5′-dimethyl-2,2′-bipyridine)nickel(II)]
title_sort di 956 1 1 azido bis azido 5 5 8242 dimethyl 2 2 8242 bipyridine nickel ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536808037902
work_keys_str_mv AT jinhou di95611azidobisazido558242dimethyl228242bipyridinenickelii