{2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II)
In the title complex, [Ni(C30H23O2P2)I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are ref...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811008828 |
| _version_ | 1818948393822584832 |
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| author | Abderrahmen Salah Davit Zargarian |
| author_facet | Abderrahmen Salah Davit Zargarian |
| author_sort | Abderrahmen Salah |
| collection | DOAJ |
| description | In the title complex, [Ni(C30H23O2P2)I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anticipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves. |
| first_indexed | 2024-12-20T08:46:06Z |
| format | Article |
| id | doaj.art-9706b89e1f8b4cb093e128caf003c81d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:46:06Z |
| publishDate | 2011-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-9706b89e1f8b4cb093e128caf003c81d2022-12-21T19:46:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-04-01674m437m43710.1107/S1600536811008828{2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II)Abderrahmen SalahDavit ZargarianIn the title complex, [Ni(C30H23O2P2)I], the divalent Ni atom is coordinated by two P atoms and one C atom from the 1,3-bis[(diphenylphosphanyl)oxy]benzene ligand; the distorted square-planar geometry is completed by an iodide ligand. The largest distortions from ideal square-planar geometry are reflected in the P—Ni—P angle of 164.20 (2)° and the P—Ni—C angles of 82.09 (6) and 82.11 (6)°. The rather short Ni—C bond length [1.890 (2) Å] is anticipated in light of the much stronger trans influence of the aryl moiety compared to the iodide ligand. The P-bound phenyl rings adopt different orientations to minimize steric repulsion among themselves.http://scripts.iucr.org/cgi-bin/paper?S1600536811008828 |
| spellingShingle | Abderrahmen Salah Davit Zargarian {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) Acta Crystallographica Section E |
| title | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) |
| title_full | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) |
| title_fullStr | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) |
| title_full_unstemmed | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) |
| title_short | {2,6-Bis[(diphenylphosphanyl)oxy]phenyl-κ3P,C1,P′}iodidonickel(II) |
| title_sort | 2 6 bis diphenylphosphanyl oxy phenyl amp 954 3p c1 p amp 8242 iodidonickel ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811008828 |
| work_keys_str_mv | AT abderrahmensalah 26bisdiphenylphosphanyloxyphenylamp9543pc1pamp8242iodidonickelii AT davitzargarian 26bisdiphenylphosphanyloxyphenylamp9543pc1pamp8242iodidonickelii |